Find the emf of the cell in which the following reaction takes place at 298 K:
\(\mathrm{Ni}(\mathrm{s})+2 \mathrm{Ag}^{+}(0.001 \mathrm{M}) \rightarrow \mathrm{Ni}^{2+}(0.001 \mathrm{M})+2 \mathrm{Ag}(\mathrm{s}) \)
\( \small{\text { (Given that } \mathrm{E}_{\text {cell }}^{\circ}=10.5 \mathrm{~V}, \frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.059 \text { at } \ 298 \mathrm{~K})} \)
1. 1.05 V
2. 1.0385 V
3. 1.385 V
4. 0.9615 V
In the electrochemical cell:
the emf of this Daniel cell is E1. When the concentration of ZnSO4 is changed to 1.0 M and that of CuSO4 is changed to 0.01 M, the emf changes to E2. From the following, which one is the relationship between E1 and E2 ?
(Given, \(\frac{RT}{F}\) = 0.059)
1.
2.
3.
4.
The pressure of H2 required to make the potential of H2 - electrode zero in pure water at 298 K is:
1. | 10-12 atm | 2. | 10-10 atm |
3. | 10-4 atm | 4. | 10-14 atm |
For a given reaction,
Cu(s) + 2Ag+ (aq) → Cu2+(aq)+2Ag(s);
E0=0.46 V at 298 K . The equilibrium constant will be :
1.
2.
3.
4.
A hypothetical electrochemical cell is shown below.
A|A+(x M) || B+(y M)|B
The Emf measured is +0.20 V. The cell reaction is:
1. A+ + B → A + B+
2. A+ + e- → A ; B+ + e- → B
3. The cell reaction cannot be predicted.
4. A + B+ → A+ + B