Consider the following relations for emf of an electrochemical cell:

(a) emf of cell = (Oxidation potential of anode) – (Reduction potential of cathode)
(b) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode)
(c) emf of cell = (Reduction potential of anode) + (Reduction potential of cathode)
(d) emf of cell = (Oxidation potential of anode) – (Oxidation potential of cathode)

The correct relation among the given options is: 

1. (a) and (b) 2. (c) and (d)
3. (b) and (d) 4. (c) and (a)

Subtopic:  Electrode & Electrode Potential |
 68%
From NCERT
AIPMT - 2010
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Molar conductivities (°m) at infinite dilution of
NaCl, HCl, and CH3COONa are 126.4, 425.9, and 91.0 S cm2 mol-1 respectively.
 (°m)  for CH3COOH  will be: 

1. \(180.5~S~cm^2~mol^{-1}\) 2. \(290.8~S~cm^2~mol^{-1}\)
3. \(390.5~S~cm^2~mol^{-1}\) 4. \(425.5~S~cm^2~mol^{-1}\)
Subtopic:   Kohlrausch Law & Cell Constant |
 91%
From NCERT
AIPMT - 2012
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The correct increasing order of reducing power of the metals is:

K+/K = –2.93 V
Ag+/Ag = 0.80 V
Hg2+/Hg = 0.79 V
Mg2+/Mg = –2.37 V
Cr3+/Cr = – 0.74 V
 
1. Cr<Mg<K<Ag<Hg 2. Mg<K<Ag<Hg<Cr
3. K<Ag<Hg<Cr<Mg 4. Ag<Hg<Cr<Mg<K

Subtopic:  Electrode & Electrode Potential |
 85%
From NCERT
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The correct statement about the given galvanic cell equation is -

Zn(s) + 2Ag+­­­(aq) → Zn2+(aq) + 2Ag(s)

1. The current will flow from silver to zinc in the external circuit.
2. The current will flow from zinc to silver in the external circuit.
3. The current will flow from silver to zinc in the internal circuit.
4. The current will flow from zinc to silver in the internal circuit.

Subtopic:  Electrolytic & Electrochemical Cell |
 61%
From NCERT
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 2Cr(s) + 3Cd2+(aq)  2Cr3+(aq) + 3Cd

ECr3+/Cr= -0.74 VECd2+/Cd=-0.40 V

The value of Gro in the above reaction will be-

1. -196.83 kJ

2. 196.83 kJ

3. 186.83 kJ

4. -186.83 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
 74%
From NCERT
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The incorrect statement(s) among the below is/are:

a. The unit of conductivity is S cm-2
b. Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration.
c. The unit of molar conductivity is S cm2 mol-1
d. Molar conductivity increases with an increase in concentration.

1. a

2. a and d

3. b and d

4. a and c

Subtopic:  Conductance & Conductivity |
 57%
From NCERT
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The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. The molar conductivity will be -

1. 124 S cm2 mol-1 2. 134 S cm2 mol-1
3. 128 S cm2 mol-1 4. 136 S cm2 mol-1
Subtopic:  Conductance & Conductivity |
 88%
From NCERT
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The electricity required in coulombs for the oxidation of 1 mole of FeO to Fe2Ois:

1. 964.87 C 2. 96487 C
3. 96.487 C 4. 9.6487 C
Subtopic:  Faraday’s Law of Electrolysis |
 86%
From NCERT
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\(Fe^{2+}(aq) \ + \ Ag^{+}(aq) \ \rightarrow \ Fe^{3+}(aq) \ + \ Ag(s)\)

\(E_{Fe^{3+}/Fe^{2+}}^{o} \ = \ 0.77 \ V; \ E_{Ag^{+}/Ag}^{o} \ = \ 0.80 \ V\)

The value of \(\Delta G_{r}^{o} \)  in 
the above reaction will be:

1. +2.89 kJ

2. -2.89 kJ

3. -2.89 J

4. -186.83 J

Subtopic:  Relation between Emf, G, Kc & pH |
 82%
From NCERT
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The value of Ecell in the reaction below will be:

\(\small{Pt(s)|Br^{-}(0.010 \ M)|Br_{2}(l) \ ||H^{+}(0.030 \ M)|H_{2}(g)(1 \ bar)|Pt(s)}\)

\(E_{Br^{-}/Br_{2}}^{o} \ = \ -1.09 \ V\)

1. +1.298 V

2. -1.398 V

3. -1.298 V

4. -1.198 V

Subtopic:  Nernst Equation |
From NCERT
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