$\mathrm{Benzene}+{\mathrm{CH}}_3\mathrm{Cl}\stackrel{{\mathrm{AlCl}}_3}{\to }<mspace\; width="1em"></mspace>{\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_3$

The mechanism & intermediate involved in the above reaction are:

1. Aromatic electrophilic substitution & carbocation

2. Aromatic Nucleophilic substitution & carbanion

3. Aromatic free radical substitution & Free radical

4. Carbene based substitution reaction & Carbene

The products formed after ozonolysis of Pent-2-ene are:

Decreasing order of acidic behavior of benzene, n-hexane, and ethyne is:

1. Hexane > Ethyne > Benzene

2. Benzene > Hexane > Ethyne

3. Ethyne > Benzene > Hexane

4. Benzene > Ethyne > Hexene

$\mathrm{Ethyne}<mspace\; width="1em"></mspace>\stackrel{?}{\to }$ $\mathrm{Benzene}$ 

The reagent used in the above conversion is:

1. Cr₂O₃

2. Alc. KOH

3. Red hot Fe

4. NaNH₂/liq.NH₃

The correct order of decreasing reactivity of the following compounds:

Chlorobenzene, 2,4-Dinitrochlorobenzene, and p-Nitrochlorobenzene

with an electrophile (E⁺)  is :

The product(s) obtained via oxymercuration (HgSO₄ + H₂SO₄ ) of but-1-yne is -

1. ${\mathrm{CH}}_3{\mathrm{CH}}_2-\stackrel{\stackrel{\mathrm{O}}{\left|\right|}}{\mathrm{C}}-{\mathrm{CH}}_3$

2. CH₃CH₂ CH₂-CHO

3. CH₃CH₂CHO + HCHO

4. CH₃ CH₂COOH + HCOOH

Which of the following hydrocarbon fuels has the highest octane rating?

1. Methane

2. Ethane

3. Iso-octane

4. Triptane

Baeyer's reagent is: 

1. Acidified permanganate solution

2. Alkaline permanganate solution

3. Neutral permanganate solution

4. Aqueous bromine solution

Anti-Markovnikov’s addition of HBr is not observed in-

Which compound among the following has the highest boiling point?