What is the hybridization shown by C1 and C2 carbons, respectively in the given compound?

\( OHC-CH=CH-{^2}CH_2-{^1}COOCH_3\)
 
1. sp2 and sp3 2. sp2 and sp2
3. sp3 and sp2 4. sp3 and sp3

Subtopic:  Hybridisation & Structure of Carbon Compounds |
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Select the correct option based on the statements below:
Assertion (A): Chlorine is an electron-withdrawing group, yet it exhibits ortho- and para-directing behavior in electrophilic aromatic substitution.
Reason (R): Inductive effect of chlorine destabilises the intermediate carbocation formed during the electrophilic substitution, however due to the more pronounced resonance effect, the halogen stabilises the carbocation at ortho and para positions.
  
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
Subtopic:  Electron Displacement Effects |
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The most stable carbocation among the following is:
1. 2.
3. 4.
Subtopic:  Reaction Intermediates ; Preparation & Properties |
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Match list-I with list-II:

List-I List-II
(a) Separation of aniline-water mixture (i) Fractional distillation
(b) Separation of aniline-chloroform mixture (ii) Distillation under reduced pressure
(c) Separation of glycerol from spent-lye (iii) Distillation
(d) Separation of different fractions of crude oil (iv) Steam distillation
Choose the correct answer from the options given below:
(a) (b) (c) (d)
1. (i) (iii) (ii) (iv)
2. (iv) (i) (iii) (ii)
3. (iv) (ii) (iii) (i)
4. (iv) (iii) (ii) (i)
Subtopic:  Purification of Organic Compounds |
 70%
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The correct IUPAC name of the following compound is : 

1. 6-bromo-4-methyl-2-chlorohexan-4-ol
2. 1-bromo-5-chloro-4-methylhexan-3-ol
3. 6-bromo-2-chloro-4-methylhaxan-4-ol
4. 1-bromo-4-methyl-5-chorohexan-3-ol
Subtopic:  Nomenclature |
 74%
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The Kjeldahl's method for the estimation of nitrogen can be used to estimate the amount of nitrogen in which one of the following compounds?
1. 2.
3. 4.
Subtopic:  Purification of Organic Compounds |
 63%
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In Lassaigne's extract of an organic compound both nitrogen and sulphur are present which gives blood red colour with \(Fe^{3+}\) due to the formation of:
1. \([\mathrm{Fe}(\mathrm{SCN})]^{2+} \)
2. \(\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3 \cdot \times \mathrm{H}_2 \mathrm{O} \)
3. \(\mathrm{NaSCN} \)
4. \(\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]^{4-} \)
Subtopic:  Qualitative Analysis of Organic Compounds |
 59%
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The number of \(\sigma\)  bonds, \(\pi\) bonds and lone pair of electrons in pyridine respectively are: 
1. 12, 2, 1
2. 11, 2, 0 
3. 12, 3, 0 
4. 11, 3, 1
Subtopic:  Hybridisation & Structure of Carbon Compounds |
 63%
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Match List -I with List-II 
List-I
(Mixtures/Sample)
List-II
(Technique used for purification)
A Glycerol from spent lye (I) Steam distillation
B Chloroform + Aniline  (II) Fractional distillation
C Fractions of crude oil (III) Distillation under reduced pressure
D Aniline+water (IV) Distillation 
Choose the correct answer from the options given below 
Options: (A) (B) (C) (D)
1. III IV II I
2. IV II I III
3. I II III IV
4. I III II IV
Subtopic:  Purification of Organic Compounds |
 70%
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Given below are two statement:
I: In an organic compound, when inductive and electromeric effects operate in opposite directions, the inductive effect predominates.
II: Hyperconjugation is observed in o-xylene.
In the light of the above statements, choose the correct answer from the options given below:
1. Statement I is true but Statement II is false.
2. Statement I is false but Statement II is true
3. Both Statement I and Statement II are true.
4. Both Statement I and Statement II are false.
Subtopic:  Electron Displacement Effects |
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