Reversible expansion of an ideal gas under isothermal and adiabatic conditions are as shown in the figure:

 

AB$\to$Isothermal expansion

AC$\to$Adiabatic expansion

Which of the following options is not correct?

1. $∆S_{isothermal}>∆S_{adiabatic}$

2. $T_A=T_B$

3. $W_{isothermal}>W_{adiabatic}$

4. $T_C>T_A$

An ideal gas expands isothermally from ${10}^{-3}{m}^3 to {10}^{-2} m^3$ at 300 K against a constant pressure of ${10}^5 N{m}^{-2}$. The work done by  the gas is:

A process among the following shows decrease in entropy is :

1. $2\mathrm{H}\left(\mathrm{(g}\right)$)$\to$ ${\mathrm{H}}_2\left(\mathrm{(g)}\right)$

2. Evaporation of water

3. Expansion of a gas at a constant temperature

4. Sublimation of solid to gas

Under the isothermal condition, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is:
[Given that 1 L bar = 100 J]

1. 30 J

2. -30 J

3. 5 kJ

4. 25 J

The enthalpy of combustion of H₂, cyclohexene (C₆H₁₀) and cyclohexane (C₆H₁₂) are -241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is:

1. -121 kJ per mol

2. +121 kJ per mol

3. +242 kJ per mol

4. -242 kJ per mol

The enthalpy and entropy change for the reaction: Br₂ (l) + Cl₂ (g) →2BrCl(g), are 30kJ mol^-1 and 105 JK^-1 mol^-1 respectively. The temperature at which the reaction will be in equilibrium is: 

1. 285.7 K

2. 273 K

3. 450 K

4. 300 K

Assuming each reaction is carried out in an open container,
Reaction that shows ΔH=ΔE is :

1. $H_2\left(g\right)+B{r}_2\left(g\right)\to 2HBr\left(g\right)$

2. $C\left(s\right)+2H_{2}O\left(g\right)\to 2H_2\left(g\right)+C{O}_2\left(g\right)$

3. $PC{l}_5\left(g\right)\to PC{l}_3\left(g\right)+C{l}_2\left(g\right)$

4. $2CO\left(g\right)+O_2\left(g\right)\to 2C{O}_2\left(g\right)$

Identify the correct statement for change of Gibbs energy for a system (ΔG_system) at constant temperature and pressure:

The bond energy of H—H and Cl-Cl is 430 kJ mol^-1 and 240 kJ mol^-1 respectively
and ΔH_f for HCl is -90 kJ mol^-1. The bond enthalpy of HCl is:

1. 290 $kJ$ $mo{l}^{-1}$

2. 380 $kJ$ $mo{l}^{-1}$

3. 425 $kJ$ $mo{l}^{-1}$

4. 245 $kJ$ $mo{l}^{-1}$