The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 oC is:

1. 10.52 cal/(mol K)

2. 21.04 cal/(mol K)

3. 5.260 cal/(mol K)

4. 0.526 cal/(mol K)

Subtopic:  Thermochemistry |
 79%
From NCERT
AIPMT - 2012
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The standard enthalpy of vaporization vapHo for water at 100 oC is 40.66 kJ mol-1.
The internal energy of vaporization of water at 100 oC (in kJ mol-1) is: 
(Assume water vapour behaves like an ideal gas.)

1. +37.56

2. -43.76

3. +43.76

4. +40.66

Subtopic:  Enthalpy & Internal energy |
 59%
From NCERT
AIPMT - 2012
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Identify which of the following is the correct option for free expansion of an ideal gas under adiabatic condition.

1.  q0, T=0, W=0
2.  q=0, T=0, W=0
3.  q=0, T<0, W0
4.  q=0, T0, W=0

Subtopic:  2nd & 3rd Law of Thermodynamics | First Law of Thermodynamics |
 75%
From NCERT
AIPMT - 2011
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Given the following reaction:
\(4H(g)\)→  \(2 H_{2}\)\((g)\)
The enthalpy change for the reaction is -869.6 kJ. The dissociation energy of the H-H bond is:
1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

Subtopic:  Enthalpy & Internal energy |
 68%
From NCERT
AIPMT - 2011
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Standard entropies of X2, Y2 and XY3 are 60, 40 and 50JK-1mol-1 respectively. For the reaction 
12X2 + 32Y2   XY3 ; H = -30 kJ to be at equilibrium, the temperature should be:

1. 750 K

2. 1000 K

3. 1250 K

4. 500 K

Subtopic:  Gibbs Energy Change |
 78%
From NCERT
AIPMT - 2010
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From the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 
Enthalpy for the reaction, 

will be:

1. 1523.6 kJ mol-1 2. -243.6 kJ mol-1
3. -120.0 kJ mol-1 4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
 75%
From NCERT
AIPMT - 2009
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Links
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The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Subtopic:  Gibbs Energy Change |
 88%
From NCERT
AIPMT - 2009
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Which of the following are not state functions? 
(I) q + W 
(II) q 
(III) W 
(IV) H - TS

1. (I) and (IV)
2. (II), (III) and (IV)
3. (I), (II) and (III)
4. (II) and (III)
Subtopic:  Gibbs Energy Change |
 75%
From NCERT
AIPMT - 2008
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For the gas phase reaction, 
 PCl5(g)PCl3(g)+Cl2(g)
which of the following conditions is correct?

1. ΔH = 0 and ΔS < 0

2. ΔH > 0 and ΔS > 0

3. ΔH < 0 and ΔS < 0

4. ΔH > 0 and ΔS < 0

Subtopic:  Gibbs Energy Change |
 80%
From NCERT
AIPMT - 2008
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The standard free energies of formation(in kJ/mol) at 298 K are -237.2, -394.4, and -8.2 for H2O(l), CO2(g), and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell is:

1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V

Subtopic:  Gibbs Energy Change |
 55%
From NCERT
AIPMT - 2008
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NEET 2023 - Target Batch - Aryan Raj Singh
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NEET 2023 - Target Batch - Aryan Raj Singh