For vaporization of water at 1 atmospheric pressure, the values of ∆H and ∆S are 40.63 kJ mol^–1 and 108.8 JK^–1 mol^–1, respectively. The temperature when Gibbs energy change (∆G) for this transformation will be zero, is:

1. 393.4 K

2. 373.4 K

3. 293.4 K

4. 273.4 K

Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be:

1. 3 Joules

2. 9 Joules

3. Zero

4. Infinite

The following two reactions are known$F{e}_2{O}_3\left(s\right)+3CO\left(g\right)\to 2Fe\left(s\right)+3C{O}_2\left(g\right);$
$∆H=-26.88$ $kJ$
$FeO\left(s\right)+CO\left(g\right)\to Fe\left(s\right)+C{O}_2\left(g\right);$
$∆H=-16.5$ $kJ$

The value of $∆$H for the following reaction

$F{e}_2{O}_3\left(s\right)+CO\left(g\right)\to 2FeO\left(s\right)+C{O}_2\left(g\right)$ is:

1. -43.3 kJ

2. -10.3 kJ

3. +6.2 kJ

4. +10.3 kJ

Match List – I (Equations) with List – II (Type of processes) and select the correct option.

Equal volumes of two monoatomic gases, A and B, at same temperature and pressure are mixed. The ratio of specific heats (Cp/Cv) of the mixture will be:
1.  1.50
2.  3.3
3.  1.67
4.  0.83

Consider the following processes:

                                       ∆H (kJ/mol)
½ A → B                            + 150
3B → 2C + D                      –125
E + A → 2D                        +350

For B + D → E + 2C, ∆H will be-

1. 325 kJ/mol 

2. 525 kJ/mol

3. –175 kJ.mol 

4. –325 kJ/mol

The enthalpy of combustion of H₂, cyclohexene (C₆H₁₀) and cyclohexane (C₆H₁₂) are -241, -3800 and -3920 kJ per mol respectively. Heat of hydrogenation of cyclohexene is:

1. -121 kJ per mol

2. +121 kJ per mol

3. +242 kJ per mol

4. -242 kJ per mol

The enthalpy and entropy change for the reaction: Br₂ (l) + Cl₂ (g) →2BrCl(g), are 30kJ mol^-1 and 105 JK^-1 mol^-1 respectively. The temperature at which the reaction will be in equilibrium is: 

1. 285.7 K

2. 273 K

3. 450 K

4. 300 K