Assertion (A): | ICl is more reactive than I₂. |
Reason (R): | I-Cl bond is weaker than I-I bond. |
1. | (A) is False but (R) is True. |
2. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
3. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
4. | (A) is True but (R) is False. |
Given below are two statements:
Assertion (A): | Fluorine exhibits only –1 oxidation state whereas other halogens exhibit + 1, + 3, + 5 and + 7 oxidation states. |
Reason (R): | Other halogens have d orbitals and therefore, can expand their octets and show +1, +3, +5 and +7 oxidation states also. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Given below are two statements:
Assertion (A): | Although electron gain enthalpy of fluorine is less negative as compared to chlorine, fluorine is a stronger oxidising agent than chlorine. |
Reason (R): | F2 has low enthalpy of dissociation and F– has high hydration enthalpy |
The correct option is-
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | The atomic size of F is smaller than that of Cl. |
Reason (R): | F-F bond is stronger than the Cl-Cl bond. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Assertion (A): | NaCl reacts with concentrated H2SO4 to give colourless fumes with a pungent smell. But on adding MnO2, the fumes become greenish-yellow. |
Reason (R): | MnO2 oxidizes HCl to chlorine gas which is greenish-yellow. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | HI cannot be prepared by the reaction of KI with concentrated H2SO4. |
Reason (R): | HI has the lowest H—X bond strength among halogen acids. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Statement I: | Acid strength increases in the order given as HF < HCl < HBr < HI. |
Statement II: | As the size of the elements F, Cl, Br, I increases down the group, the bond strength of HF, HCI, HBr, and HI decreases and so the acid strength increases. |
1. | Statement I is correct and Statement II is incorrect |
2. | Statement I is incorrect and Statement II is correct. |
3. | Both Statement I and Statement II are correct. |
4. | Both Statement I and Statement II are incorrect. |
Which of the following statements are correct?
a. | Among halogens, the radius ratio between iodine and fluorine is maximum. |
b. | Leaving F — F bond, all halogens have weaker X — X bond than X — X' bond in interhalogens. |
c. | Among interhalogen compounds a maximum number of atoms are present in iodine fluoride. |
d. | Interhalogen compounds are more reactive than halogen compounds. |
1. (a, b, c)
2. (b, c, d)
3. (a, c, d)
4. (a, b, d)
Consider the following statements about halogens:
(I) |
\(I_2< F_2< Br_2<Cl_2\) The bond dissociation energies for halogens are in the order: |
(II) | The only oxidation state is -1. |
(III) | The energy required for the excitation of electrons to the first excited state decreases progressively as we move from F to I. |
(IV) | \(HX^-_2\) species in their aqueous solutions (X = halogen). | They form
Which of the following sets includes the correct statements?
1. I, II, IV
2. I, III, IV
3. II, III, IV
4. I, III
Match the substance given in Column I with the application given in Column II and mark the appropriate option:
Column I (Substance) |
Column II (Application) |
||
A. | Liquid helium | (i) | Chlorinating agent |
B. | Argon | (ii) | Inert atmosphere (metallurgy) |
C. | PCl5 | (iii) | Cryogenics |
D. | P4O10 | (iv) | Dehydrating agent |
A | B | C | D | |
1. | (iii) | (ii) | (i) | (iv) |
2. | (iii) | (iv) | (i) | (ii) |
3. | (ii) | (iii) | (i) | (iv) |
4. | (ii) | (iv) | (i) | (iii) |