In the reaction, N₂O₄ $\rightleftharpoons$ 2NO₂, $\mathrm{\alpha }$ is that part of N₂O₄ which dissociates. The number of moles at equilibrium will be:

1. ${\left(1-\mathrm{\alpha }\right)}^2$

2. $3\mathrm{\alpha }$

3. $\mathrm{\alpha }$

4. $1+\mathrm{\alpha }$

The dissociation of NH₄OH can be suppressed by the addition of

The Ksp of Ag₂CrO₄, AgCl, AgBr and Agl are, respectively, 1.1x10^-12, 1.8x10^-10, 5.0x10^-13, and 8.3x10^-17. The salt precipitates that last if the AgNO₃ solution is added to the solution containing equal moles of NaCl, NaBr, Nal and Na₂CrO₄ is -

Inert gas is added to the equilibrium ${\mathrm{PCl}}_5(\mathrm{g}) \rightleftharpoons {\mathrm{PCl}}_3(\mathrm{g})$ $+$ ${\mathrm{Cl}}_2\left(\mathrm{g}\right)$ at constant pressure. The degree of dissociation will :

1. Remain unchanged

2. Decrease

3. Increase

4. Decrease or increase but cannot be predicted with certainty

The most hydrolyzed salt among the following is-

(Assume that K_b of all weak bases is the same)
1. NH₄Cl
2. CuSO₄
3. AlCl₃
4. All are equally hydrolyzed.

In an acidic Buffer solution (CH₃COOH + CH₃COONa), the species mainly present in the solution are:

(Ignore negligible amount)

1. CH₃COOH, CH₃COO^-, CH₃COONa, H⁺

2. CH₃COO^-, Na⁺, CH₃COOH

3. CH₃COONa, CH₃COO-, H⁺

4. CH₃COO^-, Na⁺, H⁺, CH₃COONa

For the equilibrium of the reaction, HgO(s) $\stackrel{}{\rightleftharpoons }$ Hg(g) + $\frac{1}{2}$O₂(g), K_P for the reaction at a total pressure of "P" will be:

HI was heated in a sealed tube at 440$°$C till the equilibrium was reached. At this point, HI was found to be 22 % decomposed. The equilibrium constant for this dissociation is :

Salting out action of the soap is based on:

1. Complex ion formation

2. Common ion effect

3. Solubility product

4. Acid-base neutralization

In which of the following will the solubility of AgCl be the minimum?