At a certain temperature and pressure of 105 Pa, iodine vapour contains 40% by volume of I atoms. The Kp for the equilibrium of the reaction would be-

 I2 (g)  2I (g)

1. 2.67 × 10Pa

2. 1.00 × 10Pa

3. 3.63 × 10Pa

4. 2.18 × 105 Pa

Subtopic:  Kp, Kc & Factors Affecting them |
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Given the reaction 2HI (g)  H2 (g) + I2 (g)

A sample of HI(g) is placed in a flask at a pressure of 0.2 atm. At equilibrium, the partial pressure of HI(g) is 0.04 atm.  The KP for the given equilibrium would be:

1. 2.0 2. 3.5
3. 4.0 4. 2.6
Subtopic:  Kp, Kc & Factors Affecting them |
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A mixture of 1.57 mol of N2, 1.92 mol of H2, and 8.13 mol of NH3 is introduced into a 20 L vessel at 500 K. At this temperature, the equilibrium constant, Kc for the reaction N2 (g) + 3H2 (g)  2NH3 (g) is 1.7 × 102.

The direction of the net reaction is:

1. Reaction is at equilibrium.

2. Reaction will proceed in forwarding direction.

3. Reaction will proceed in the backward direction.

4. Data is not sufficient.

Subtopic:  Kp, Kc & Factors Affecting them |
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Given the reaction:

2BrCl (g)  Br2 (g) + Cl2 (g); Kc= 32 at 500 K. If the initial concentration of BrCl is 3.3 × 10-3 mol L–1, the molar concentration of BrCl in the mixture at equilibrium would be:

1. 3.0 × 10-2 molL-1

2. 2.0 × 10-4 molL-1

3. 2.5 × 10-6 molL-1

4. 3.0 × 10-4 molL-1

Subtopic:  Kp, Kc & Factors Affecting them |
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For the reaction, NO(g) + 1/2O2 (g) ⇌ NO2(g)

 ∆fG° (NO2) = 52.0 kJ/mol , ∆fG° (NO) = 87.0 kJ/mol and
fG° (O2) = 0 kJ/mol. 
The equilibrium constant for the formation of NOfrom
NO and O2 at 298K would be

1. 2.36 × 104 

2. 3.10 × 107

3. 1.36 × 106

4. 2.18 × 105

Subtopic:  Kp, Kc & Factors Affecting them |
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The equilibrium constant for the following reaction is 1.6 ×105 at 1024K

H2(g) + Br2(g)  2HBr(g)

If HBr at pressure 10.0 bar is introduced into a sealed container at 1024 K, the equilibrium pressure of HBr will be :

1. 11.20 bar

2. 5.56 bar

3. 7.30 bar

4. 9.95 bar

Subtopic:  Kp, Kc & Factors Affecting them |
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For the reaction, 2NOCl (g)  2NO (g) + Cl2 (g); Kp= 1.8 × 10–2 atm at 500 K.

The value of Kc for above mentioned reaction would be:

1. 4.33 × 10-4 mol L-1
2. 4.33 × 104 mol L-1
3. 1.65 × 10-5 mol L-1
4. 2.39 × 10-3 mol L-1

Subtopic:  Kp, Kc & Factors Affecting them |
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For the following equilibrium, Kc= 6.3 × 1014 at 1000 K

NO(g) + O3 (g)  NO2(g) + O2 (g) 

The value of Kc for the reverse reaction is:

1. 2.33 × 10-16
2. 1.59 × 10-15
3. 2.67 × 10-13
4. 4.47 × 1014

Subtopic:  Kp, Kc & Factors Affecting them |
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\(\mathrm{K}_{\mathrm{c}}=\frac{\left[\mathrm{NH}_3\right]^4\left[\mathrm{O}_2\right]^5}{[\mathrm{NO}]^4\left[\mathrm{H}_2 \mathrm{O}]^6\right.}\)
The balanced chemical equation corresponding to the above-mentioned expression is:

1. \(4 \mathrm{NO}_{(\mathrm{g})}+6 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons 4 \mathrm{NH}_{3(\mathrm{g})}+5 \mathrm{O}_{2(\mathrm{g})} \)
2. \(4 \mathrm{NH}_3(\mathrm{g})+5 \mathrm{O}_{2(\mathrm{g})} \rightleftharpoons 4 \mathrm{NO}_{(\mathrm{g})}+6 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\)
3. \(\ 2 \mathrm{NO}_{(\mathrm{g})}+3 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons 4 \mathrm{NH}_{3(\mathrm{g})}+3 \mathrm{O}_{2(\mathrm{g})}\)
4. \(\ \mathrm{NH}_{3(\mathrm{g})}+3 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})} \rightleftharpoons 2 \mathrm{NO}_{(\mathrm{g})}+3 \mathrm{O}_{2(\mathrm{g})}\)
Subtopic:  Kp, Kc & Factors Affecting them |
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One mole of H2O and one mole of CO are taken in a 10 L vessel and heated to
725
 K. At equilibrium, 40% of water(by mass) reacts with CO according to the equation,

H2O (g) + CO (g)  H2 (g) + CO2 (g)

The equilibrium constant for the above-mentioned reaction would be:

1. 0.66 2. 0.35
3. 0.44 4. 0.82


 

Subtopic:  Kp, Kc & Factors Affecting them |
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