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Match the complex ions give in Column I with the colours given in column II and assign the correct code.

               Column I

            (Complex ion)

              Column II

              (Colour)

A. [Co(NH3)6]3+

1. Violet

B. [Ti(H2O)6)]3+

2. Green

C. Ni(H2O62+

3. Pale blue 

D. Ni(H2O)4(en)2+

4. Yellowish orange

Codes:

Options:  A   B   C   D 
1. 2 3 4 1
2. 3 1 5 2
3. 5 4 3 2
4. 4 3 2 1

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Given below are two statements:
Assertion (A): Cr(H2O6)Cl2 and Fe(H2O)6Cl2 are reducing in nature.
Reason (R): Unpaired electrons are present in their d-orbitals.
 
1. Both (A) and (R) are True, and (R) is the correct explanation of (A).
2. Both (A) and (R) are True, and (R) is not the correct explanation of (A).
3. (A) is True, but the (R) is False.
4. (A) is False, but (R) is True.
Subtopic:  VBT, CFT & their Limitations |
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IUPAC name of H2[PtCl6] is:

1. hydrogen hexachloroplatinate (IV)

2. dihydrogen hexachloroplatinate (IV)

3. hydrogen hexachloroplatinic (IV) acid

4. hexachloroplatinic (IV) acid

Subtopic:  Introduction, Classification and Nomenclature |
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Which of the following complexes is not expected to exhibit isomerism?

1. [Ni(NH3)4(H2O)2]2+ 2. [Ni(NH3)2Cl2]
3. [Pt(NH3)2Cl2] 4. [Ni(en)3]2+
Subtopic:  Isomerism in Coordination Compounds |
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Given the following pair of isomers:
[Cr(NH3)6][Cr(NO2)6] and
[Cr(NH3)4(NO2)2][Cr(NH3)2(NO2)4]
Aside from X-ray diffraction, how could the following pairs of isomers be distinguished from one another?

1. Cryoscopic method
2. Measuring their molar conductance
3. Measuring their magnetic moments
4. Observing their colors

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For the complexes [Co(NH3)6]Cl3 and [Co(NH3)6]Cl2​, identify the correct matching property from the given options.

\([Co(NH_3)_6]Cl_3\) \([Co(NH_3)_6]Cl_2\)
1. Stability less more
2. Magnetism Paramagnetic      Diamagnetic
3. Hybridization \(sp^3d^2\) \(d^2sp^3\)
4. Complex Inner orbital Outer orbital
Subtopic:  VBT, CFT & their Limitations |
Level 4: Below 35%
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The IUPAC name of [Pt(NH3)2Cl2] [PtBr4] is:
 
1. Diamminedichloridoplatium (II) tetrabromidoplatinate (IV) 
2. Diamminedichloridoplatinum (III) tetrabromidoplatinate (III) 
3. Diamminedichloridoplatinum (IV) tetrabromidoplatinate (II)
4. Diamminedichloridoplatinum (IV) tetrabromidoplatinum (II)  
 
 
Subtopic:  Introduction, Classification and Nomenclature |
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In which of the following complexes, the central atom has \(sp^3\) hybridisation? 
1. \([PtCl_4]^{2-}\)
2. \([Ni(CN)_4]^{2-}\)
3. \([Cu(NH_3)_4]^{2+}\)
4. None of the above.
Subtopic:  VBT, CFT & their Limitations |
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What are the geometries of \([Ni(CO)_4]\) and \([Ni(PPh_3)_2Cl_2]\) respectively?

1. Both square planar.

2. Tetrahedral and square planar, respectively.

3. Both tetrahedral.

4. Square planar and tetrahedral, respectively.

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Which of the following compounds can show geometrical isomerism? 
1. \([Pt(NH_3)_2 Cl_2]\)
2. \([Zn(NH_3)_2 Cl_2]\)
3. \([Pt(NH_3)_3 Cl]\)
4. Both (1) and (2) 
Subtopic:  Isomerism in Coordination Compounds |
Level 3: 35%-60%
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