The correct order of spin-only magnetic moment for the given complexes is: 

1. \([Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} > [Fe(CN)_6]^{3-} \)
2. \([Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} > [MnCl_6]^{3-} \)
3. \([MnCl_6]^{3-} >[Fe(CN)_6]^{3-} >[Co(H_2O)_6]^{2+} \)
4. \([MnCl_6]^{3-} > [Co(H_2O_6]^{2+} > [Fe(CN)_6]^{3-} \)

Match Column I with Column II, Columns I and II represent complexes and magnetic moment (BM) respectively. 

Choose the correct answer from the options given below:

What is the correct electronic configuration of the central atom in ${\mathrm{K}}_4\left[\mathrm{Fe}{\left(\mathrm{CN}\right)}_6\right]$ based on crystal field theory:

1. ${\mathrm{e}}^4 {\mathrm{t}}_{2\mathrm{g}}^{ 2}$

2. ${\mathrm{t}}_{2\mathrm{g}}^{ 4} {\mathrm{e}}_{\mathrm{g}}^2$

3. ${\mathrm{t}}_{2\mathrm{g}}^{ 6} {\mathrm{e}}_{\mathrm{g}}^0$

4. ${\mathrm{e}}^3 {\mathrm{t}}_{2\mathrm{g}}^{ 3}$

The crystal field stabilization energy (CFSE) for [CoCl₆]^4- is 18000 cm^-1.
The CFSE for [CoCl₄]^2-  will be:

1. $6000$ $c{m}^{-1}$

2. $16000$ $c{m}^{-1}$

3. $18000$ $c{m}^{-1}$

4. $8000$ $c{m}^{-1}$

The correct increasing order for the wavelengths of absorption in complexes of Co³⁺ is:

1. [Co(H₂O)₆]³⁺ < [Co(en)₃]³⁺ < [Co(NH₃)₆]^{3 +}

2. [Co(H₂O)₆]³⁺ <  [Co(NH₃)₆]³⁺ <  [Co(en)₃]³⁺

3. [Co(NH₃)₆]³⁺ < [Co(en)₃]³⁺ < [Co(H₂O)₆]³⁺

4. [Co(en)₃]³⁺ <  [Co(NH₃)₆]³⁺ < [Co(H₂O)₆]³⁺

The correct statement among the following regarding [Mn(CN)₆]^3-is:

1. It is sp³d² hybridized and tetrahedral.

2. It is d²sp³ hybridized and octahedral.

3. It is dsp² hybridised and square planar.

4. It is sp³d² hybridised and octahedral.

The hybridization involved in the complex ${\left[\mathrm{Ni}{\left(\mathrm{CN}\right)}_4\right]}^{2-}$is:
(Atomic number of Ni=28)

1. $ds{p}^2$

2. $s{p}^3$

3. $d^{2}s{p}^2$

4. $d^{2}s{p}^3$