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Q. No.Out of the following complex compounds, which of the compounds will have the minimum conductance in solution?
a.
\(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3 \)
b.
\(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl} \)
c.
\(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right] \)
d.
\(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]\)
1.
a and b
2.
a,b, and c
3.
c and d
4.
b, c, and d
Subtopic: Introduction, Classification and Nomenclature |
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Match List-I with List-II:
Choose the correct answer from the options given below:
| List-I | List-II | ||
| A. | Haber process | I. | Fe catalyst |
| B. | Wacker oxidation | II. | \(PdCl_2\) |
| C. | Wilkinson catalyst | III. | \([PPh_3)_3 RhCl]\) |
| D. | Ziegler catalyst | IV. | \(TiCl_4~ \text {with}~ Al(CH_3)_3\) |
| 1. | A-I, B-II, C-III, D-IV | 2. | A-I, B-IV, C-III, P-II |
| 3. | A-I, B-II, C-IV, D-III | 4. | A-II, B-III, C-I, D-IV |
Subtopic: Organometallic Complexes & their Uses |
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Which of the following are paramagnetic?
Choose the correct answer from the options given below:
| A. | \(\left[{NiCl}_4\right]^{2-}\) | B. | \(Ni(CO)_4\) |
| C. | \(\left[{Ni}({CN})_4\right]^{2-}\) | D. | \(\left[{Ni}\left({H}_2 {O}\right)_6\right]^{2+}\) |
| E. | \({Ni}\left({PPh}_3\right)_4\) | ||
| 1. | A and D only | 2. | A, D and E only |
| 3. | A and C only | 4. | B and E only |
Subtopic: VBT, CFT & their Limitations |
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The correct order of the wavelength of light absorbed by the following complexes is.
Choose the correct answer from the options given below:
| A. | \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+} \) | B. | \(\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-} \) |
| C. | \(\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_4\right]^{2+} \) | D. | \(\left[\mathrm{Ti}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}\) |
| 1. | C < D < A < B | 2. | C < A < D < B |
| 3. | B < D < A < C | 4. | B < A < D < C |
Subtopic: VBT, CFT & their Limitations |
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Match the following:
Choose the correct answer from the options given below:
1. A-I, B-III, C-IV, D-II
2. A-III, B-IV, C-I, D-II
3. A-IV, B-I, C-III, D-II
4. A-III, B-I, C-IV, D-II
| List I (Complex/ ion) |
List II (Shape/geometry) |
||
| A. | \([Pt(Cl_2)(NH_3)_2]\) | I. | Octahedral |
| B. | \([Co(NH_3)_6]Cl_3\) | II. | Trigonal bipyramidal |
| C. | \([NiCl_4]^{2-}\) | III. | Square planar |
| D. | \([Fe(CO)_5]\) | IV. | Tetrahedral |
Choose the correct answer from the options given below:
1. A-I, B-III, C-IV, D-II
2. A-III, B-IV, C-I, D-II
3. A-IV, B-I, C-III, D-II
4. A-III, B-I, C-IV, D-II
Subtopic: VBT, CFT & their Limitations |
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Which one of the following is an ambidentate ligand?
1. Ethylenediaminetetraacetate ion
2. Oxalate
3. Ethane-1,2-diamine
4. Thiocyanate
1. Ethylenediaminetetraacetate ion
2. Oxalate
3. Ethane-1,2-diamine
4. Thiocyanate
Subtopic: Ligands |
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Match List I with List II:
Choose the correct answer from the options given below:
1. A-III, B-I, C-II, D-IV
2. A-I, B-III, C-II, D-IV
3. A-III, B-I, C-IV, D-II
4. A-II, B-IV, C-III, D-I
| List-I | List-II | ||
| A. | \([{Pt(NH_3)_2Cl_2}]\) | I. | Optical |
| B. | \([Co(en)_3]^{3+}\) | II. | Solvate |
| C. | \([Co(NH_3)_5NO_2]Cl_2\) | III. | Geometrical |
| D. | \([Cr(H_2O)_6]Cl_3\) | IV. | Linkage |
Choose the correct answer from the options given below:
1. A-III, B-I, C-II, D-IV
2. A-I, B-III, C-II, D-IV
3. A-III, B-I, C-IV, D-II
4. A-II, B-IV, C-III, D-I
Subtopic: Isomerism in Coordination Compounds |
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The formula of tetraammineaquachloridocobalt(III) chloride is:
| 1. | [Co(NH3)4(H2O)Cl]Cl2 |
| 2. | [Co(NH3)4Cl2] × H2O |
| 3. | [Co(NH3)4]Cl3 × H2O |
| 4. | [Co(NH3)4(H2O)Cl]Cl |
Subtopic: Introduction, Classification and Nomenclature |
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Given below are two statements:
(Given \(\left.\mathrm{oxH}_2=\mathrm{HOOC}-\mathrm{COOH}\right)\)
In light of the above statements, choose the most appropriate answer from the options given below:
| Statement-I: | [Fe(ox)3]3- is chiral. |
| Statement-II: | trans-[Cr(H2O)2(ox)2]- is chiral. |
(Given \(\left.\mathrm{oxH}_2=\mathrm{HOOC}-\mathrm{COOH}\right)\)
In light of the above statements, choose the most appropriate answer from the options given below:
| 1. | Statement-I is incorrect but Statement-II is correct. |
| 2. | Both Statement-I and Statement-II are correct. |
| 3. | Both Statement-I and Statement-II are incorrect. |
| 4. | Statement-I is correct but Statement-II is incorrect. |
Subtopic: Isomerism in Coordination Compounds |
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The complex which has facial and meridional isomers is:
(Given : py = pyridine and en = H2N-CH2-CH2-NH2)
(Given : py = pyridine and en = H2N-CH2-CH2-NH2)
| 1. | [Ni(en)2(H2O)2]2+ |
| 2. | [Cr(py)3(Cl)3] |
| 3. | [Cr(H2O)6]3+ |
| 4. | [Co(NH3)4(H2O)2]3+ |
Subtopic: Isomerism in Coordination Compounds |
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