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Q. No.Identify the incorrect statement about \(\mathrm{PCl_5}\).
1.
\(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles.
2.
All five \(\mathrm{P-Cl}\) bonds are identical in length.
3.
\(\mathrm{PCl_5}\) exhibits sp3d hybridisation.
4.
\(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds.
Subtopic: Group 15 - Preparation, Properties & Uses |
79%
Level 2: 60%+
NEET - 2024
Hints
Identify the incorrect statement from the following:
| 1. | The acidic strength of HX (X=F, Cl, Br and I) follows the order: HF > HCI > HBr >HI |
| 2. | Fluorine exhibits - 1 oxidation state whereas other halogens exhibit +1, +3, +5 and +7 oxidation states also. |
| 3. | The enthalpy of dissociation of F2 is smaller than that of Cl2. |
| 4. | Fluorine is stronger oxidising agent than chlorine. |
Subtopic: Group 17 - Preparation, Properties & Uses |
71%
Level 2: 60%+
NEET - 2024
Hints
Identify the incorrect statement.
| 1. | \(\mathrm{PEt}_3\) and \(\mathrm{Asph}_3\) as ligands can form \(\mathrm{d} \pi-\mathrm{d} \pi\) bond with transition metals. |
| 2. | The \(\mathrm{N}-\mathrm{N}\) single bond is as strong as the \(\mathrm{P}-\mathrm{P}\) single bond. |
| 3. | Nitrogen has unique ability to form \(\mathrm{p \pi-p \pi}\) multiple bonds with nitrogen, carbon and oxygen. |
| 4. | Nitrogen cannot form \(\mathrm{d} \pi-\mathrm{p} \pi\) bond as other heavier elements of its group. |
Subtopic: Group 15 - Preparation, Properties & Uses |
78%
Level 2: 60%+
NEET - 2024
Hints
Given below are two statements :
In the light of the above statements, choose the correct answer from the options given below:
1. Both Statement I and Statement II are false.
2. Statement I is true and Statement II is false
3. Statement I is false but Statement II is true.
4. Both Statement I and Statement II are true.
| Statement I: | The boiling point of hydrides of Group 16 elements follow the order \(\text{H}_2 \text{O}>\text{H}_2 \text{Te}>\text{H}_2 \text{Se}>\text{H}_2 \text{S} .\) |
| Statement II: | On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point. |
1. Both Statement I and Statement II are false.
2. Statement I is true and Statement II is false
3. Statement I is false but Statement II is true.
4. Both Statement I and Statement II are true.
Subtopic: Group 16 - Preparation, Properties & Uses |
72%
Level 2: 60%+
NEET - 2024
Hints
Subtopic: Group 16 - Preparation, Properties & Uses |
70%
Level 2: 60%+
NEET - 2024
Hints
Given below are two statements :
In light of the above statements, choose the most appropriate answer from the options given below:
| Statement I: | Like nitrogen that can form ammonia, arsenic can form arsine. |
| Statement II: | Antimony cannot form antimony pentoxide. |
In light of the above statements, choose the most appropriate answer from the options given below:
| 1. | Statement I is correct but Statement II is incorrect |
| 2. | Statement I is incorrect but Statement II is correct |
| 3. | Both Statement I and Statement II are correct |
| 4. | Both Statement I and Statement II are incorrect |
Subtopic: Group 15 - Preparation, Properties & Uses |
Level 3: 35%-60%
NEET - 2025
Please attempt this question first.
Hints
Please attempt this question first.
Match the Oxoacids of Sulphur given in List-I with the number of bonds given in List-II and mark the correct option.
Choose the correct answer from the options given below:
| List-I (Oxoacids of Sulphur) |
List-II (Bonds) |
||
| A. | Peroxodisulphuric acid | I. | Two S-OH, Four S=O, One S-O-S |
| B. | Sulphuric acid | II. | Two S-OH, One S=O |
| C. | Pyrosulphuric acid | III. | Two S-OH, Four S=O, One S-O-O-S |
| D. | Sulphurous acid | IV. | Two S-OH, Two S=O |
| Options: | A | B | C | D |
| 1. | III | IV | II | I |
| 2. | I | III | II | IV |
| 3. | III | IV | I | II |
| 4. | I | III | IV | II |
Subtopic: Group 16 - Preparation, Properties & Uses |
73%
Level 2: 60%+
NEET - 2023
Hints
Fluorine is a stronger oxidizing agent than chlorine because:
Choose the most appropriate answer from the options given :
| (a) | F–F bond has a low enthalpy of dissociation. |
| (b) | Flouride ion (F–) has high hydration enthalpy. |
| (c) | Electron gain enthalpy of fluorine is less negative than chlorine. |
| (d) | Fluorine has a very small size. |
Choose the most appropriate answer from the options given :
| 1. | (a) and (b) only | 2. | (a) and (c) only |
| 3. | (a) and (d) only | 4. | (b) and (c) only |
Subtopic: Group 17 - Preparation, Properties & Uses |
Level 3: 35%-60%
NEET - 2022
Hints
The reaction that is a part of large scale industrial preparation of nitric acid is:
| 1. | \(\mathrm{NaNO}_3+\mathrm{H}_2 \mathrm{SO}_4\xrightarrow[500~K, \ 9\text{ bar}]{Pt} \mathrm{NaHSO}_4+\mathrm{HNO}_3\) |
| 2. | \(4 \mathrm{NH}_3+5 \mathrm{O}_2 \text{(from air)}\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{NO}+6 \mathrm{H}_2 \mathrm{O}\) |
| 3. | \(4 \mathrm{HPO}_3+2 \mathrm{~N}_2 \mathrm{O}_5\xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{P}_4 \mathrm{O}_{10}\) |
| 4. | \(\mathrm{Cu}\left(\mathrm{NO}_3\right)_2+2 \mathrm{NO}_2+2 \mathrm{H}_2 \mathrm{O} \\ \xrightarrow[500~K, \ 9\text{ bar}]{Pt} 4 \mathrm{HNO}_3+\mathrm{Cu}\) |
Subtopic: Group 15 - Preparation, Properties & Uses |
59%
Level 3: 35%-60%
NEET - 2022
Hints
Chlorine shows the bleaching action in the presence of moisture due to the formation of
1. HOCl
2. HOClO
3. H2O2
4. O atom
Subtopic: Group 17 - Preparation, Properties & Uses |
Level 3: 35%-60%
NEET - 2022
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