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| Reagents | Products | |
| (a) | HBF4 | Ph – F |
| (b) | CuCN/KCN | Ph – CN |
| (c) | CuCl2/HCl | Ph – Cl |
| (d) | Ph – NH2 | Ph – N = N – Ph |
| Statement I: | Benzendiazonium chloride is a colourless crystalline solid. It is insoluble in water but reacts with water when warmed. |
| Statement II: | Benzendiazonium chloride on reacting with HCI in presence of copper powder gives chlorobenzene as the product. This is an example of Gatterman reaction. |
| 1. | Both Statement I and Statement II is true. |
| 2. | Both Statement I and Statement II is false. |
| 3. | Statement I is true but Statement II is false. |
| 4. | Statement I is false but Statement II is true. |
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| 1. | NaNO2/HCl; Sn/HCl; Br2; H2O/H3PO2 |
| 2. | Sn/HCl; NaNO2/HCl; Br2; H2O/H3PO2 |
| 3. | Br2; Sn/HCl; NaNO2/HCl; H2O/H3PO2 |
| 4. | Sn/HCl; Br2; NaNO2/HCl; H2O/H3PO2 |