A mixture of 1 mol of benzene and 1 mol of nitrobenzene is reacted with 1 mol of acetyl chloride in the presence of AlCl3. The major product(s) is/are:
1. Acetophenone 
2. 3-Nitroacetophenone
3. 1:1 Mixture of acetophenone and 3-Nitroacetophenone
4. 1,3-Diacetyl benzene
Subtopic:  Urea & Nitro Compound |
Level 3: 35%-60%
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When nitrobenzene is treated with bromine in the presence of FeBr3
the major product formed is m-bromonitrobenzene.
The statement related to obtaining the m-isomer is:
1. The intermediate carbonium ion formed after the initial attack of Br+ at the meta position is the least stabilised.
2. The electron density on the meta carbon is higher than that on the ortho and para positions.
3. Loss of aromaticity when Br+ attacks at the ortho and para positions and not at the meta position.
4. None of the above.
Subtopic:  Urea & Nitro Compound |
Level 4: Below 35%
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