In the following reaction sequence,  
 
the major products X and Z are:
 
1.
2.
3.
4.

Subtopic:  Amines - Preparation & Properties | Mechanism |
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Match the organic compounds given in List–I with their corresponding pKb given in List–II:
Amine (List–I) List - II pKb (aqueous medium)
A. Aniline (i) 9.0
B. Ethanamine (ii) 3.29
C. N-Ethylethanamine (iii) 3.25
D. N,N-diethylethanamine (iv) 3.0
 
A B C D
1. (i) (ii) (iv) (iii)
2. (i) (iv) (iii) (ii)
3. (i) (ii) (iii) (iv)
4. (ii) (iii) (iv) (i)
Subtopic:  Amines - Preparation & Properties |
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The correct matches of reagents that are used to react with diazonium salt \((Ph-N^+_2X^-) \) to get the product given against each reagent are:
Reagents Products
(a) HBF Ph – F
(b) CuCN/KCN Ph – CN
(c) CuCl2/HCl  Ph – Cl
(d) Ph – NH Ph – N = N – Ph
1. (a) and (b)
2. (a), (b), and (c)
3. (a), (b), (c), and (d)
4. (a), (b), and (d)
Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
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Which of the following is the correct sequence of reagents for converting 4-nitrotoluene to 2-bromotoluene?

1. NaNO2/HCl; Sn/HCl; Br2; H2O/H3PO2
2. Sn/HCl; NaNO2/HCl; Br2; H2O/H3PO2
3. Br2; Sn/HCl; NaNO2/HCl; H2O/H3PO2
4. Sn/HCl; Br2; NaNO2/HCl; H2O/H3PO2
Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
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The most basic nitrogen in the given molecule is :

1. A
2. B
3. C
4. D

Subtopic:  Amines - Preparation & Properties |
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The product (major) formed in the given organic reaction, A, is: 

1. 2.
3. 4.
Subtopic:  Amines - Preparation & Properties |
 58%
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For the following ions, choose the correct statement:
 
1. III is the most stable in aqueous phase
2. I is the most stable in the aqueous phase
3. III is the smallest in size
4. II is the most stable in the aqueous phase



 
Subtopic:  Amines - Preparation & Properties |
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A mixture of 1 mol of benzene and 1 mol of nitrobenzene is reacted with 1 mol of acetyl chloride in the presence of AlCl3. The major product(s) is/are:
1. Acetophenone 
2. 3-Nitroacetophenone
3. 1:1 Mixture of acetophenone and 3-Nitroacetophenone
4. 1,3-Diacetyl benzene
Subtopic:  Urea & Nitro Compound |
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Assertion (A): Anilinium chloride is more acidic than ammonium chloride.
Reason (R): The anilinium ion is resonance-stabilised.
 
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True statement but (R) is False.
4. Both (A) and (R) are False statements.
Subtopic:  Mechanism |
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Consider the given two statements:
Assertion (A): p-Toluidine is a stronger base than m-toluidine.
Reason (R): The methyl group from m-position exerts a smaller electron-donating inductive (+l) effect than from p-position.
Options:
1. Both (A) and (R) are True and (R) is the correct explanation for (A).
2. Both (A) and (R) are True but (R) is not the correct explanation for (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
Subtopic:  Amines - Preparation & Properties |
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