Assertion (A): | p-Toluidine is a stronger base than m-toluidine. |
Reason (R): | The methyl group from m-position exerts a smaller electron-donating inductive (+l) effect than from p-position. |
1. | Both (A) and (R) are True and (R) is the correct explanation for (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation for (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Anilinium chloride is more acidic than ammonium chloride. |
Reason (R): | The anilinium ion is resonance-stabilised. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True statement but (R) is False. |
4. | Both (A) and (R) are False statements. |
1. | Acetophenone |
2. | 3-Nitroacetophenone |
3. | 1:1 Mixture of acetophenone and 3-Nitroacetophenone |
4. | 1,3-Diacetyl benzene |
1. | 2. | ||
3. | 4. |
Assertion (A): | In strongly acidic solutions, aniline becomes more reactive towards electrophilic reagents. |
Reason (R): | The amino group being completely protonated in a strongly acidic solution, the lone pair of electrons on the nitrogen is no longer available for resonance |
1. | Both (A) & (R) are True and the reason is the correct explanation of the (A). |
2. | Both (A) & (R) are True but the reason is not the correct explanation of the (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
1. | The intermediate carbonium ion formed after the initial attack of Br+ at the meta position is the least stabilised. |
2. | The electron density on meta carbon is higher than that on ortho and para positions. |
3. | Loss of aromaticity when Br+ attacks at the ortho and para positions and not at the meta position. |
4. | None of the above. |
Statement I: | In the Hofmann rearrangement reaction, the alkyl group shifts from a carbonyl carbon atom to the nitrogen atom. |
Statement II: | The tertiary amine formed in Hofman rearrangement reaction contains one carbon less than that present in the original amide. |
1. | Both Statement I & Statement II are true. |
2. | Both Statement I & Statement II are false. |
3. | Statement I is true while Statement II is false. |
4. | Statement I is false while Statement II is true. |
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