Among the following amines, the strongest Bronsted base is:

1. 2.
3. 4.

Subtopic:  Amines - Preparation & Properties |
 62%
Level 2: 60%+
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The correct decreasing order of basic strength of the following species is.

H2O,NH3,OH,NH2

1.NH2>OH>NH3>H2O
2.OH>NH2>H2O>NH3
3.NH3>H2O>NH2>OH
4.H2O>NH3>OH>NH2

Subtopic:  Amines - Preparation & Properties |
 59%
Level 3: 35%-60%
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Which of the following should be most volatile?

I.  \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{NH}_2\)
II.  \(\left(\mathrm{CH}_3\right)_3 \mathrm{~N}\)
III. 
IV.  \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_3\)

 

1. II 2. IV
3. I 4. III
Subtopic:  Amines - Preparation & Properties |
 50%
Level 3: 35%-60%
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Which of the following methods of preparation of amines will not give the same number of carbon atoms in the chain of amines as in the reactant?

1. Reaction of nitrile with LiAlH4
2. Reaction of amide with LiAlH4 followed by treatment with water
3. Heating alkyl halide with potassium salt of phthalimide followed by hydrolysis
4. Treatment of amide with bromine in an aqueous solution of sodium hydroxide.

Subtopic:  Amines - Preparation & Properties |
 82%
Level 1: 80%+
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The compound(s) among the following that is/are not typically synthesized using the Sandmeyer reaction:

(a) Chlorobenzene

(b) Bromobenzene

(c) Iodobenzene 

(d) Fluorobenzene

Choose the correct option:
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 86%
Level 1: 80%+
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Reduction of nitrobenzene by which of the following reagent gives aniline?

(a) Sn/HCl
(b) Fe/HCl
(c) H2-pd
(d) Sn/NH4OH

Choose the correct option
1. (a, b, c)
2. (b, c, d)
3. (a, c, d)
4. (a, b, d)

Subtopic:  Amines - Preparation & Properties |
 87%
Level 1: 80%+
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Which of the following species are involved in the carbylamine test?

a.  R—NC
b.  CHCl3
c.  COCl2
d.  NaNO2 + HCl

Choose the correct option
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Identification of Primary, Secondary & Tertiary Amines |
 87%
Level 1: 80%+
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Which of the following reagents can be used to convert benzene diazonium chloride to benzene?

a. SnCl2 / HCI
b. CH3CH2OH
c. H3PO2
d. LiAlH4

Choose the correct option:
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 82%
Level 1: 80%+
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The product of the above reaction is ............

Choose the correct option

1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)
Subtopic:  Mechanism |
 89%
Level 1: 80%+
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Arenium ion involved in the bromination of aniline is ......

Choose the correct option
1. (a, b, c)
2. (b, c, d)
3. (a, c, d)
4. (a, b, d)

Subtopic:  Mechanism |
 57%
Level 3: 35%-60%
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