Acid anhydrides on reaction with primary amines give:

1.  Amide

2.  Imide

3.  Secondary amine

4.  Imine

Subtopic:  Mechanism |
 68%
Level 2: 60%+
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The following reaction is named as:

\(\mathrm{Ar} \mathrm{N}_2^{+} \mathrm{Cl}^{-} \xrightarrow{\mathrm{Cu}/ \mathrm{HCl}} \mathrm{ArCl}+\mathrm{N}_2+\mathrm{CuCl}\)
1. Sandmeyer reaction
2. Gattermann reaction
3. Claisen reaction
4. Carbylamine reaction

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 73%
Level 2: 60%+
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Which of the following compound will not undergo azo coupling reaction with benzene diazonium chloride?

1.  Aniline

2.  Phenol

3.  Anisole

4.  Nitrobenzene

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 62%
Level 2: 60%+
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A compound among the following that does not undergo an azo coupling reaction with benzene diazonium chloride is:

1. Aniline

2. Phenol

3. Anisole

4. Nitrobenzene

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 62%
Level 2: 60%+
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Which of the following compounds is the weakest Bronsted base?

1. 2.
3. 4.
Subtopic:  Amines - Preparation & Properties |
 51%
Level 3: 35%-60%
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Among the following amines, the strongest Bronsted base is:

1. 2.
3. 4.
Subtopic:  Amines - Preparation & Properties |
 62%
Level 2: 60%+
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The correct decreasing order of basic strength of the following species is.

H2O,NH3,OH,NH2

1.NH2>OH>NH3>H2O
2.OH>NH2>H2O>NH3
3.NH3>H2O>NH2>OH
4.H2O>NH3>OH>NH2

Subtopic:  Amines - Preparation & Properties |
 59%
Level 3: 35%-60%
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Which of the following should be most volatile?

I.  \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{NH}_2\)
II.  \(\left(\mathrm{CH}_3\right)_3 \mathrm{~N}\)
III. 
IV.  \(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_3\)

 

1. II 2. IV
3. I 4. III
Subtopic:  Amines - Preparation & Properties |
 50%
Level 3: 35%-60%
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Which of the following methods of preparation of amines will not give the same number of carbon atoms in the chain of amines as in the reactant?

1. Reaction of nitrile with LiAlH4
2. Reaction of amide with LiAlH4 followed by treatment with water
3. Heating alkyl halide with potassium salt of phthalimide followed by hydrolysis
4. Treatment of amide with bromine in an aqueous solution of sodium hydroxide.

Subtopic:  Amines - Preparation & Properties |
 82%
Level 1: 80%+
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The compound(s) among the following that is/are not typically synthesized using the Sandmeyer reaction:

(a) Chlorobenzene

(b) Bromobenzene

(c) Iodobenzene 

(d) Fluorobenzene

Choose the correct option:
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, d)

Subtopic:  Diazonium Salts: Preparation, Properties & Uses |
 86%
Level 1: 80%+
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