Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type Pd(C6H5)2(NCS)2 and Pd(C6H5)2(SCN)2 are:

1. Linkage isomers   
2. Coordination isomers
3. Ionization isomers 
4. Geometrical isomers

Subtopic:  Isomerism in Coordination Compounds |
 90%
Level 1: 80%+
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The compounds [Co(SO4 (NH3)5 ]Br and [Co(SO4 (NH3)5] Cl classified as:

1. Linkage isomerism 2. Ionisation isomerism
3. Coordination isomerism 4. No isomerism
Subtopic:  Isomerism in Coordination Compounds |
 55%
Level 3: 35%-60%
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Which of the following species is not expected to be a ligand?

1.  NO

2.  NH4+

3.  NH2CH2CH2NH2

4.  CO

Subtopic:  Ligands |
 87%
Level 1: 80%+
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Which of the following species is not expected to be a ligand?

1. NO

2. NH4+

3. NH2CH2CH2NH2

4. CO

Subtopic:  Ligands |
 94%
Level 1: 80%+
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What kind of isomerism exists between [Cr(H2O)6]Cl(violet) and [Cr(H2O)5Cl]Cl2⋅H2O (greyish-green)?

1. Linkage isomerism

2. Solvate isomerism

3. lonisation isomerism

4. Coordination isomerism

Subtopic:  Isomerism in Coordination Compounds |
 88%
Level 1: 80%+
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IUPAC name of [Pt(NH3)2Cl(NO2)] is:

1. Platinum diaminechloronitrite

2. Chloronitrito-N-ammineplatinum (ll)

3. Diamminechloridonitrito-N-platinum (ll)

4. Diamminechloronitrito-N-platinate (ll)

Subtopic:  Introduction, Classification and Nomenclature |
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Level 1: 80%+
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Atomic number of Mn Fe and Co are 25, 26 and 27 respectively. Which of the following inner orbital octahedral complex ions are diamagnetic?

a. CoNH363+

b. Mn(CN)63-

c.  Fe(CN)64-

d.  FeCN63-

Choose the correct option
1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)

Subtopic:  VBT, CFT & their Limitations |
 61%
Level 2: 60%+
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Identify the outer orbital octahedral complexes among the following that have the same number of unpaired electrons:
(Atomic numbers of Mn, Fe, Co, and Ni are 25, 26, 27, and 28 respectively)

(a) MnCl63- (b) FeF63-
(c) CoF63- (d) NiNH362+


1. (a, b)
2. (b, c)
3. (c, d)
4. (a, c)

Subtopic:  VBT, CFT & their Limitations |
 69%
Level 2: 60%+
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Which of the following options are correct for Fe(CN)63- is: 

a.  d2sp3 hybridisation 

b.  d2sp2 hybridisation 

c.  Paramagnetic 

d.  Diamagnetic

Choose the correct option:

1. (a, b) 2. (b, c)
3. (c, d) 4. (a, c)
Subtopic:  Organometallic Complexes & their Uses |
 88%
Level 1: 80%+
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An aqueous pink solution of cobalt(II) chloride changes to deep blue on the addition of excess of HCl. This is because:

a. \([Co(H_2O)_6]^{2+}\) is transformed into \([CoCl_6]^{4-}\)
b. \([Co(H_2O)_6]^{2+}\) is transformed into \([CoCl_4]^{2-}\)
c. Tetrahedral complexes have smaller crystal field splitting than octahedral complexes
d. Tetrahedral complexes have larger crystal field splitting than octahedral complexes


Choose the correct option:
1. a and b
2. b and c
3. c and d
4. a and c

Subtopic:  VBT, CFT & their Limitations |
Level 3: 35%-60%
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