The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of the transition element, which shows the highest magnetic moment.
| 1. | 2. | ||
| 3. | 4. |
Which of the following oxidation state is common for all lanthanoids?
| 1. | +2 | 2. | +3 |
| 3. | +4 | 4. | +5 |
Gadolinium (atomic number 64) is an element of the 4f series, Identify the correct electronic configuration of gadolinium from the following options:
\(1. (X e) 4 f^{7} 5 d^{1} 6 s^{2} \)
2. \( (X e) 4 f^{6} 5 d^{2} 6 s^{2}\)
3. \((X e) 4 f^{8} 6 d^{2}\)
4. \((X e) 4 f^{9} 5 s^{1}\)
Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. Which of the following is not the characteristic property of interstitial compounds?
| 1. | They have high melting points in comparison to pure metals |
| 2. | They are very hard |
| 3. | They are conductor. |
| 4. | They are chemically very reactive |
The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Determine the spin only magnetic moment value of ion:
| 1. | 2.87 BM | 2. | 3.87 BM |
| 3. | 3.47 BM | 4. | 3.57 BM |
Why is the highest oxidation state of manganese in fluorides +4 (as in MnF4), while the highest oxidation state in oxides is +7 (as in Mn2O7)?
| 1. | Fluorine is more electronegative than oxygen |
| 2. | Fluorine does not possess d orbitals |
| 3. | Fluorine stabilises a lower oxidation state |
| 4. | In covalent compounds, fluorine can form a single bond only, while oxygen forms a double bond |
Although zirconium belongs to 4d transition series and hafnium to 5d transition series even then they show similar physical and chemical properties because:
| 1. | Both belong to d-block |
| 2. | Both have same number of electrons |
| 3. | Both have similar atomic radius |
| 4. | Both belong to the same group of the Periodic Table |
In the titration of KMnO₄ or its use as an oxidizing agent, the medium is acidified with dilute H₂SO₄ rather than HCl because:
| 1. | Both HCl and KMnO4 act as oxidising agents |
| 2. | KMnO4 oxidises HCl into Cl2, which is also an oxidising agent |
| 3. | KMnO4 is a weaker oxidising agent than HCl |
| 4. | KMnO4 acts as a reducing agent in the presence of HCl |
A pair of ions that have the same electronic configuration among their constituent species is:
1. \(Sr^{3+}, Cr^{3+}\)
2. \(Fe^{3+}, Mn^{2+}\)
3. \(Fe^{3+}, Co^{3+}\)
4. \(Cr^{3+}, Fe^{3+}\)
Electronic configuration of a transition element X in +3 oxidation state is [Ar]. What is its atomic number?
| 1. | 25 | 2. | 26 |
| 3. | 27 | 4. | 24 |