Match the laws/colligative properties given in Column-I with expressions given in Column-II.
Column-I | Column-II | ||
A. | Raoult’s law | I. | \(\mathrm{\pi=C R T}\) |
B. | Osmotic pressure | II. | \(\Delta \mathrm{T}_{\mathrm{f}}=\mathrm{K}_{\mathrm{f}} \mathrm{~m}\) |
C. | Elevation of boiling point | III. | \(\mathrm{p=x_1 p_1^0+x_2 p_2^0}\) |
D. | Depression in freezing point | IV. | \(\Delta \mathrm{T}_{\mathrm{b}}=\mathrm{K}_{\mathrm{b}} \mathrm{~m}\) |
Codes:
A | B | C | D | |
1. | I | III | IV | I |
2. | I | II | III | IV |
3. | I | IV | III | II |
4. | III | I | IV | II |
The freezing point of depression constant (Kf ) of benzene is 5.12 K kg mol–1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is:
(rounded off up to two decimal places)
1. 0.80 K
2. 0.40 K
3. 0.60 K
4. 0.20 K
Freezing point of an aqueous solution is -0.166C. Elevation of boiling point of same solution would be-
(Kb = 0.512 K m-1 and Kf = 1.66 K m-1)
1. | 0.18°C | 2. | 0.05°C |
3. | 0.09°C | 4. | 0.23°C |
In comparison to a 0.01 M solution of glucose, the depression in the freezing point of a 0.01 M MgCl2 solution will be:
1. | Same | 2. | About twice |
3. | About three times | 4. | About six times |