| (i) | \(\mathrm{{CO}(g)+{H}_{2} O(g) \rightleftharpoons {CO}_{2}(g)+{H}_{2}(g) ; K_{1}}\) |
| (ii) | \(\mathrm{CH}_{4}(\mathrm{g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \rightleftharpoons \mathrm{CO}(\mathrm{g})+3 \mathrm{H}_{2}(\mathrm{g); K_{2}}\) |
| (iii) | \(\mathrm{CH}_{4}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \rightleftharpoons \mathrm{CO}_{2}(\mathrm{g})+4 \mathrm{H}_{2}(\mathrm{g) ; K_{3}}\) |
Given:
Kb = 1.6 × 10⁻⁸
| 1. | \(s=\left(\frac{K_{s p}}{106}\right)^{1 / 4}~ \) | 2. | \(s=\left(\frac{K_{s p}}{108}\right)^{1 / 5} \) |
| 3. | \(s=\left(\frac{K_{s p}}{81}\right)^{1 / 5} \) | 4. | \(s=\left(\frac{K_{s p}}{48}\right)^{1 / 5} \) |
| 1. | 1.1 × 10–13 M | 2. | 1.1 × 10–7 M |
| 3. | 5.5 × 10–7 M | 4. | 5.5 × 10–8 M |
| 1. | It may be changed by the addition of a catalyst. |
| 2. | It increases if the concentration of one of the products increases. |
| 3. | It changes with changes in temperature. |
| 4. | It increases if the concentration of one of the reactants is increased. |
naA + nbB ⇌ ncC + ndD
if the equilibrium constant for
aA + bB ⇌ cC + dD
is Kc.
1. n√Kc