| 1. | \(1.0 \times 10^{-4}\) | 2. | \(1.0 \times 10^{-10} \) |
| 3. | \( 1.0 \times 10^{10} \) | 4. | \( 1.0 \times 10^{14} \) |
| (A) | \(0.01 \mathrm{M} \ \mathrm{HCl} \) |
| (B) | \( 0.01 \mathrm{M}\ \mathrm{NaOH} \) |
| (C) | \( 0.01 \mathrm{M} \ \mathrm{CH}_3 \mathrm{COONa}\) |
| (D) | \(0.01 \mathrm{M} \ \mathrm{NaCl} \) |
| Assertion (A): | For every chemical reaction at equilibrium, standard Gibbs energy of the reaction is zero. |
| Reason (R): | At constant temperature and pressure, chemical reactions are spontaneous in the direction of decreasing Gibbs energy. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
Which is the correct expression for pKb in the following reaction?
\(\mathrm{H}_2 \mathrm{O}+\mathrm{NH}_3 \rightleftharpoons {\mathrm{NH}_4^{+}} \ + \mathrm{HO}^{-}\)| 1. | \(pK_{b} \ = \ log\frac{[H_{2}O][NH_{3}]}{[NH_{4}^{+}][OH^{-}]}\) |
| 2. | \(\)\(pK_{b} \ = \ log\frac{[OH^{-}][NH_{4}^{+}]}{[NH_{3}][H_{2}O]}\) |
| 3. | \(pK_{b} \ = -\ log\frac{[H_{2}O][NH_{3}]}{[NH_{4}^{+}][OH^{-}]}\) |
| 4. | \(pK_{b} \ = \ log\frac{[NH_{3}][NH_{4}^{+}]}{[OH^{-}][H_2O]}\) |
| Assertion (A): | The solubilities of two sparingly soluble salts, Ni(OH)2 and AgCN with a Ksp of \(4 \times 10^{-8} ~and~1 \times 10^{-10}~mol/L\)respectively. |
| Reason (R): | AgCN is less soluble than Ni(OH)2 |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |
| Assertion (A): | Salts of strong acid and strong base do not undergo hydrolysis. |
| Reason (R): | These salts undergo hydration. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
| Assertion (A): | For the reaction: H2(g) + I2(g) \(\rightleftharpoons\) 2HI(g), if the volume of the vessel is reduced to half of its original volume, the equilibrium concentration of all gases will be doubled. |
| Reason (R): | According to Le-Chatelier's principle, reaction shifts in a direction that tends to minimize the effect of stress. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | (A) is False but (R) is True. |