The K_sp of Ag₂CrO₄ and AgBr is 1.1 × 10^–12 and 5.0 × 10^–13 respectively.

The molarity ratio of saturated solutions of Ag₂CrO₄ and AgBr will be:

1.	91.9	2.	108.6
3.	56.9	4.	76.9

The minimum volume of water required to dissolve 1g of calcium sulphate at 298 K is

(For CaSO₄ , K_sp is 9.1 × 10^–6)

1. 1.22 L

2. 0.69 L

3. 2.44 L

4. 1.87 L

A sample of pure PCl₅ was introduced into an evacuated vessel at 473 K.
After equilibrium was attained, a concentration of PCl₅ 
was found to be 0.5 × 10^–1 mol L^–1. If the value of
 K_c is 8.3 × 10^–3 mol L^–1, the concentrations of
PCl₃ and Cl₂ at equilibrium would be:

PCl_5 (g)  $\leftrightharpoons \hspace{0.17em}$PCl_3 (g) + Cl_2(g)
 

Match the standard free energy of the reaction with the corresponding equilibrium constant:

Codes:

Match the following species with the corresponding conjugate acid:

Codes

Given below are two statements: 

PCl₅, PCl₃, and Cl₂ are at equilibrium at 500 K in a closed container and their concentrations are 0.8×10^–3 mol L^–1 , 1.2×10^–3 mol L^–1 and 1.2×10^–3 mol L^–1, respectively.
The value of  K_c  for the reaction PCl₅(g) ⇌ PCl₃(g) + Cl₂(g) will be:
1. 1.8 × 10³ mol L^–1
2. 1.8 × 10³
3. 1.8 × 10^–3 mol L^–1
4. 0.55 × 10⁴

The ionisation constant of an acid, K_a , is the measure of the strength of an acid. The K_a values of acetic acid, hypochlorous acid and formic acid are $1.74\times {10}^{-5},<mspace\; width="1em"></mspace>3.0\times {10}^{-8}$ and $1.8\times {10}^{-4}$ , respectively. The  correct order of pH value of 0.1 mol dm^-3 solutions of these acids is:

1. Acetic acid > Hypochlorous acid > Formic acid

2. Hypochlorous acid < Acetic acid > Formic acid

3. Formic acid > Hypochlorous acid > Acetic acid

4. Formic acid < Acetic acid < Hypochlorous acid

${\mathrm{K}}_{{\mathrm{a}}_1},$ ${\mathrm{K}}_{{\mathrm{a}}_2}$ $\mathrm{and}$ ${\mathrm{K}}_{{\mathrm{a}}_3}$ are the respective ionisation constants for the following reactions.
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons \mathrm{H}^{+}+\mathrm{HS}^{-}\)
\(\mathrm{HS}^{-} \rightleftharpoons \mathrm{H}^{+}+\mathrm{S}^{2-}\)
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{S}^{2-}\)
The correct relationship between ${\mathrm{K}}_{{\mathrm{a}}_1},$ ${\mathrm{K}}_{{\mathrm{a}}_2}$ $\mathrm{and}$ ${\mathrm{K}}_{{\mathrm{a}}_3}$ is:
1. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} \times \mathrm{K}_{\mathrm{a}_2} \)
2. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1}+\mathrm{K}_{\mathrm{a}_2} \)
3. \(K_{a_3}=K_{a_1}-K_{a_2} \)
4. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} / \mathrm{K}_{\mathrm{a}_2}\)

The solubility of $\mathrm{Ni}{\left(\mathrm{OH}\right)}_2$ in 0.1 M NaOH is:

K_sp ($\mathrm{Ni}{\left(\mathrm{OH}\right)}_2$)= 2x ${10}^{-15}$

1. 2 x ${10}^{-8}$ M.

2. 1 x ${10}^{-13}$ M

3. 1 x ${10}^8$ M 

4. 2 x ${10}^{-13}$