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The dissociation constants for acetic acid and HCN at 25 °C are 1.5 x 10-5 and 4.5 x 10-10, respectively. The equilibrium constant for the equilibrium, 
CN- + CH3COOH  ⇌  HCN + CH3COO- 
would be:
1. 3.0×105
2. 3.0×10-5
3. 3.0×10-4
4. 3.0×104

Subtopic:  Kp, Kc & Factors Affecting them |
Level 3: 35%-60%
AIPMT - 2009
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Equal volumes of three acid solutions of pH 3, 4 and 5 are mixed in a vessel. What will be the H+ ion concentration in the mixture?
1. 1.11×10-4 M
2. 3.7×10-4 M
3. 3.7×10-3 M
4. 1.11×10-3 M

Subtopic:  pH calculation |
 69%
Level 2: 60%+
AIPMT - 2008
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If the concentration of OH ' ions in the reaction 

Fe(OH)3(s)   Fe3+(aq) + 3OH-(aq)is 
decreased by 14 times, then the equilibrium concentration of Fe3+ will increase by:

1. 8 times

2. 16 times

3. 64 times

4. 4 times

Subtopic:  Introduction To Equilibrium |
 80%
Level 1: 80%+
AIPMT - 2008
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Equimolar solutions of the following were prepared in water separately. Which one of the solutions will record the highest pH?

1. SrCI2

2. BaCl2

3. MgCl2

4. CaCl2

Subtopic:  pH calculation |
 72%
Level 2: 60%+
AIPMT - 2008
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The dissociation equilibrium of a gas AB2 can be represented as 
 2AB2(g)  2AB(g) + B2(g) 
The degree of dissociation is ‘x’ and is small compared to 1. The expression relating the degree of dissociation (x) with equilibrium constant KP and total pressure p is:
1. (2KP/p)
2. (2Kp /p)1/3
3. (2KP/p)1/2
4. (KP/P)

Subtopic:  Kp, Kc & Factors Affecting them |
 69%
Level 2: 60%+
AIPMT - 2008
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The value of KP1 and Kp2 for the reactions
 X  Y +Z ......(i)
and A 2B ......(ii)
are in the ratio of 9 : 1. If the degree of dissociation of X and A is equal, then the total pressure at equilibrium(i) and (ii) are in the ratio:

1. 3 : 1

2. 1 : 9

3. 36 : 1

4. 1 : 1

Subtopic:  Kp, Kc & Factors Affecting them |
 62%
Level 2: 60%+
AIPMT - 2008
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The value of the equilibrium constant of the reaction 
 \(HI \left(\right. g \left.\right)\) \(\leftrightharpoons\) \(\frac{1}{2} H_{2} \left(\right. g \left.\right)\) \(+\) \(\frac{1}{2} I_{2}\) is 8.0.
The equilibrium constant of the reaction
 \(H_{2} \left(\right. g \left.\right)\) \(+\) \(I_{2} \left(\right. g \left.\right)\) \(\leftrightharpoons\) \(2 HI \left(\right. g \left.\right)\) will be-

1. \(1 \over 16\) 2. \(1 \over 64\)
3. 16 4. \(1 \over 8\)
Subtopic:  Kp, Kc & Factors Affecting them |
 87%
Level 1: 80%+
AIPMT - 2008
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The pOH of a solution at 25 °C that contains 1×10-10 M of hydronium ions is:

1. 7.00 2. 4.00 
3. 9.00 4. 1.00
Subtopic:  pH calculation |
 82%
Level 1: 80%+
AIPMT - 2007
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A weak acid, HA, has a Ka of 1.00×10-5. If 0.100 mole of this acid is dissolved in one litre of water, the percentage of acid dissociated at equilibrium is closest to:

1. 99.0%

2. 1%

3. 99.9%

4. 0.100%

Subtopic:  Salt Hydrolysis & Titration |
 69%
Level 2: 60%+
AIPMT - 2007
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The following equilibrium constants are given: 
N2 + 3H2 ⇌ 2NH3K1 
N2 + O⇌ 2NO; K2 
H2 + 1/2O2 ⇌ H2O; K3 

The equilibrium constant for the oxidation of NH3 by oxygen to give NO is:

1. K2K33/K1

2. K2K32/K1

3. K22K3/K1

4. K1K2/K3 

Subtopic:  Kp, Kc & Factors Affecting them |
 68%
Level 2: 60%+
AIPMT - 2007
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