The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 oC is:

1. 10.52 cal/(mol K) 2. 21.04 cal/(mol K)
3. 5.260 cal/(mol K) 4. 0.526 cal/(mol K)

Subtopic:  Thermochemistry |
 81%
Level 1: 80%+
AIPMT - 2012
Hints

The standard enthalpy of vaporization vapHo for water at 100 oC is 40.66 kJ mol–1. The internal energy of vaporization of water at 100 oC (in kJ mol–1) is: 
(Assume water vapour behaves like an ideal gas.)

1. +37.56 2. –43.76
3. +43.76 4. +40.66
Subtopic:  Enthalpy & Internal energy |
 61%
Level 2: 60%+
AIPMT - 2012
Hints

Identify which of the following is the correct option for free expansion of an ideal gas under adiabatic condition.
1. \(\Delta \mathrm{q} \neq 0, \Delta \mathrm{~T}=0, \mathrm{~W}=0 \)
2. \(\Delta \mathrm{q}=0, \Delta \mathrm{~T}=0, \mathrm{~W}=0 \)
3. \(\Delta \mathrm{q}=0, \Delta \mathrm{~T}<0, \mathrm{~W} \neq 0 \)
4. \(\Delta \mathrm{q}=0, \Delta \mathrm{~T} \neq 0, \mathrm{~W}=0\)
Subtopic:  2nd & 3rd Law of Thermodynamics | First Law of Thermodynamics |
 82%
Level 1: 80%+
AIPMT - 2011
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Calculate the H–H bond dissociation energy from the following reaction:

4H(g) → 2H₂(g)  ΔH = −869.6 kJ

1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

Subtopic:  Enthalpy & Internal energy |
 67%
Level 2: 60%+
AIPMT - 2011
Hints

Standard entropies of X2, Y2 and XY3 are 60, 40 and 50JK-1mol-1 respectively. For the reaction 
12X2 + 32Y2   XY3 ; H = -30 kJ to be at equilibrium, the temperature should be:

1. 750 K

2. 1000 K

3. 1250 K

4. 500 K

Subtopic:  Gibbs Energy Change |
 79%
Level 2: 60%+
AIPMT - 2010
Hints

Give the following bond energies:
H—H bond energy: 431.37 kJ mol-1 
C=C bond energy: 606.10 kJ mol-1 
C—C bond energy: 336.49 kJ mol-1 
C—H bond energy: 410.50 kJ mol-1 

Enthalpy for the following reaction will be:

1. 1523.6 kJ mol-1
2. -243.6 kJ mol-1
3. -120.0 kJ mol-1
4. 553.0 kJ mol-1
Subtopic:  Thermochemistry |
 76%
Level 2: 60%+
AIPMT - 2009
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The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK-1, respectively.
C(graphite) + CO2(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K

Subtopic:  Gibbs Energy Change |
 88%
Level 1: 80%+
AIPMT - 2009
Hints

Which of the following are not state functions? 
(I) q + W 
(II) q 
(III) W 
(IV) H - TS

1. (I) and (IV)
2. (II), (III) and (IV)
3. (I), (II) and (III)
4. (II) and (III)
Subtopic:  Gibbs Energy Change |
 79%
Level 2: 60%+
AIPMT - 2008
Hints

For the gas phase reaction, 
 PCl5(g)PCl3(g)+Cl2(g)
which of the following conditions is correct?

1. ΔH = 0 and ΔS < 0

2. ΔH > 0 and ΔS > 0

3. ΔH < 0 and ΔS < 0

4. ΔH > 0 and ΔS < 0

Subtopic:  Gibbs Energy Change |
 83%
Level 1: 80%+
AIPMT - 2008
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The standard free energies of formation(in kJ/mol) at 298 K are -237.2, -394.4, and -8.2 for H2O(l), CO2(g), and pentane (g), respectively. The value of Ecell for the pentane-oxygen fuel cell is:

1. 1.968 V
2. 2.0968 V
3. 1.0968 V
4. 0.0968 V

Subtopic:  Gibbs Energy Change |
 52%
Level 3: 35%-60%
AIPMT - 2008
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