Match the structures given in Column-I with the IUPAC names in Column-II.
Column-I (Structure) | Column-II (IUPAC Name) | ||
A. | ![]() |
(i) | 4-Bromopent-2-ene |
B. | ![]() |
(ii) | 4-Bromo-3-methylpent-2-ene |
C. | ![]() |
(iii) | 1-Bromobut-2-ene |
D. | ![]() |
(iv) | 1-Bromo-2-methylpent-2-ene |
Codes:
A | B | C | D | |
1. | (ii) | (iii) | (iv) | (i) |
2. | (i) | (ii) | (iii) | (iv) |
3. | (i) | (iv) | (iii) | (ii) |
4. | (iv) | (i) | (iii) | (ii) |
The correct match of column I (Reactions) with column II (Name of reactions) is:
Column I | Column II | ||
A. | ![]() |
1. | Fittig reaction |
B. | ![]() |
2. | Wurtz-Fittig reaction |
C. | ![]() |
3. | Finkelstein reaction |
D. | ![]() |
4. | Sandmeyer reaction |
Codes:
A | B | C | D | |
1. | 2 | 1 | 4 | 3 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 1 | 3 | 2 |
Select the correct option based on statements below:
Assertion (A): | Phosphorus chlorides (tri and Penta) are preferred over thionyl chloride for the preparation of alkyl chlorides from alcohols. |
Reason (R): | Phosphorus chlorides give pure alkyl halides. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Select the correct option based on statements below:
Assertion (A): | The boiling points of alkyl halides decrease in the order RI> RBr > RCl > RF |
Reason (R): | The boiling points of alkyl chlorides, bromides, and iodides are considerably higher than those of the hydrocarbons of comparable molecular mass. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Consider the given two statements:
Assertion (A): | KCN reacts with methyl chloride to give methyl isocyanide. |
Reason (R): | \(CN^-\) is an ambident nucleophile. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | The presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution. |
Reason (R): | The nitro group, being an electron-withdrawing group, decreases the electron density over the benzene ring. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | In monohaloarenes, further electrophilic substitution occurs at ortho and para positions. |
Reason (R): | The halogen atom is a ring deactivator. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | It is difficult to replace chlorine with -OH in chlorobenzene in comparison to that in chloroethane. |
Reason (R): | Chlorine carbon (—Cl) bond in chlorobenzene has a partial double bond character due to resonance. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Select the correct option based on statements below:
Assertion (A): | Hydrolysis of (-)-2-bromooctane proceeds with an inversion of configuration. |
Reason (R): | This reaction proceeds through the formation of a carbocation. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene. |
Reason (R): | —NO2 group is an m-directing group. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |