While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required?
1. Clamp and phenolphthalein
2. Pipette and distilled water
3. Burette and porcelain tile
4. Bunsen burner and measuring cylinder
| 1. | \(\small{3 \mathrm{MnO}_{4}^{2-}+4 \mathrm{H}^{+} \rightarrow 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+2 \mathrm{H}_{2} \mathrm{O}}\) |
| 2. | \(\small{\mathrm{MnO}_{4}^{-}+4 \mathrm{H}^{+}+4 e^{-} \rightarrow \mathrm{MnO}_{2}+2 \mathrm{H}_{2} \mathrm{O}}\) |
| 3. | \(\small{10 \mathrm{I}^{-}+2 \mathrm{MnO}_{4}^{-}+16 \mathrm{H}^{+} \rightarrow 2 \mathrm{Mn}^{2+}+8 \mathrm{H}_{2} \mathrm{O}+5 \mathrm{I}_{2}}\) |
| 4. | \(\small{8 \mathrm{MnO}_{4}^{-}+3 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-}+\mathrm{H}_{2} \mathrm{O} \rightarrow 8 \mathrm{MnO}_{2}+6 \mathrm{SO}_{4}^{2-}+2 \mathrm{OH}^{-}}\) |
Which of the following is a redox reaction?
1. NaCl + KNO3 \(\rightarrow\) NaNO3 + KCl
2. CaC2O4 + 2HCl \(\rightarrow\) CaCl2 + H2C2O4
3. Ca(OH)2 + 2NH4Cl \(\rightarrow\) CaCl2 + 2NH3 + 2H2O
4. 2K[Ag(CN)2] + Zn \(\rightarrow\) 2Ag + K2[Zn(CN)4]
Amount of oxalic acid present in a solution can be determined by its titration with KMnO4 solution in the presence of H2SO4. The titration gives unsatisfactory result when carried out in the presence of HCl, because HCl does which of the following?
1. It furnishes H+ ions in addition to those from oxalic acid
2. It reduces permanganate to Mn2+
3. It oxidises oxalic acid to carbon dioxide and water
4. It gets oxidised by oxalic acid to chlorine
| 1. | \(\mathrm{I}_2~ \text {and}~ \mathrm{Cl}_2\) only | 2. | \(\mathrm{F}_2~\text {and}~\mathrm{Cl}_2\) only |
| 3. | \(\mathrm{I}_2~\text {and}~\mathrm{Br}_2\) only | 4. | \(\mathrm{Cl}_2, \mathrm{Br}_2~\text {and}~\mathrm{I}_2\) only |
| Statement I: | Potassium hydrogen phthalate is primary standard for \(NaOH\) solution. |
| Statement II: | Phenolphthalein is used to detect completion of titration. |
| 1. | Both statement-I and statement-II are correct |
| 2. | Statement-I is correct and statement-II is incorrect |
| 3. | Statement-I is incorrect and statement-II is correct |
| 4. | Both statement-I and statement-II are incorrect |
| A. | \(\mathrm{Cu}^{+} \longrightarrow \mathrm{Cu}^{2+}+\mathrm{Cu}\) |
| B. | \(\mathrm{MnO}_4^{2-} \longrightarrow \mathrm{MnO}_4^{-}+\mathrm{MnO}_2\) |
| C. | \(\mathrm{H}_2 \mathrm{O}_2 \longrightarrow \mathrm{O}_2+\mathrm{H}_2 \mathrm{O}\) |
| D. | \(\mathrm{CrO}_4^{2-} \longrightarrow \mathrm{Cr}^{3+}+\mathrm{H}_2 \mathrm{O}\) |