| 1. | \(\small{3 \mathrm{MnO}_{4}^{2-}+4 \mathrm{H}^{+} \rightarrow 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+2 \mathrm{H}_{2} \mathrm{O}}\) |
| 2. | \(\small{\mathrm{MnO}_{4}^{-}+4 \mathrm{H}^{+}+4 e^{-} \rightarrow \mathrm{MnO}_{2}+2 \mathrm{H}_{2} \mathrm{O}}\) |
| 3. | \(\small{10 \mathrm{I}^{-}+2 \mathrm{MnO}_{4}^{-}+16 \mathrm{H}^{+} \rightarrow 2 \mathrm{Mn}^{2+}+8 \mathrm{H}_{2} \mathrm{O}+5 \mathrm{I}_{2}}\) |
| 4. | \(\small{8 \mathrm{MnO}_{4}^{-}+3 \mathrm{~S}_{2} \mathrm{O}_{3}^{2-}+\mathrm{H}_{2} \mathrm{O} \rightarrow 8 \mathrm{MnO}_{2}+6 \mathrm{SO}_{4}^{2-}+2 \mathrm{OH}^{-}}\) |
Standard reduction electrode potentials of three metals A, B and C are +0.5V , -3.0 V and -1.2 V respectively. The reducing power of these metals are:
| 1. | B >C > A | 2. | A >B > C |
| 3. | C > B >A | 4. | A > C > B |
What is the oxidation number of Cl in \(\text{CaOCl}_2\) (bleaching powder)?
1. Zero, because it contains Cl2
2. -1, because it contains Cl-
3. +1, because it contains ClO-
4. +1 and -1 because it contains ClO- and Cl-
Which of the following processes is happening at the anode (from the options given below)?
1. \(\mathrm{F}_2+2 \mathrm{e}^{-} \rightarrow 2 \mathrm{~F}^{-}\)
2. \( \mathrm{H}^{+}+\frac{1}{2} \mathrm{O}_2+2 \mathrm{e}^{-} \rightarrow \mathrm{H}_2 \mathrm{O}\)
3. \(2Cr^{3+}+7H_2O \rightarrow Cr_2O^{2-}_7 +14H^+ + 6e^-\)
4. None of the above
Which of the following is a redox reaction?
1. NaCl + KNO3 \(\rightarrow\) NaNO3 + KCl
2. CaC2O4 + 2HCl \(\rightarrow\) CaCl2 + H2C2O4
3. Ca(OH)2 + 2NH4Cl \(\rightarrow\) CaCl2 + 2NH3 + 2H2O
4. 2K[Ag(CN)2] + Zn \(\rightarrow\) 2Ag + K2[Zn(CN)4]
Amount of oxalic acid present in a solution can be determined by its titration with KMnO4 solution in the presence of H2SO4. The titration gives unsatisfactory result when carried out in the presence of HCl, because HCl does which of the following?
1. It furnishes H+ ions in addition to those from oxalic acid
2. It reduces permanganate to Mn2+
3. It oxidises oxalic acid to carbon dioxide and water
4. It gets oxidised by oxalic acid to chlorine
Galvanization is applying a coating of which of the following metal?
| 1. | Pb | 2. | Cr |
| 3. | Cu | 4. | Zn |
Given
\(\mathrm{E}_{\mathrm{Cr}^{3+} / \mathrm{Cr}}^0=-0.74 \mathrm{~V} ; \mathrm{E}_{\mathrm{MnO}_4^{-} / \mathrm{Mn}^{2+}}^0=1.51 \mathrm{V}\\{E}_{\mathrm{Cr}_2 \mathrm{O}_7^{2-} / \mathrm{Cr}^{3+}}^0=1.33 \mathrm{~V} ; \mathrm{E}_{\mathrm{Cl}_2 / \mathrm{Cl}^{-}}^0=1.36 \mathrm{~V}\)
Based on the data given above, strongest oxidizing agent will be:
| 1. | Mn2+ | 2. | |
| 3. | Cl– | 4. | Cr3+ |
Consider the following reaction :
\(a\mathrm{Cu}+b\mathrm{HNO}_{3} \rightarrow c\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}+d\mathrm{NO}+e\mathrm{H}_{2} \mathrm{O}\)
The values of a, b, and e in the reaction are, respectively:
1. 3, 8 and 4
2. 5, 2 and 8
3. 5, 2 and 16
4. 2, 5 and 8