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In solid-state, PCl5 exists as: 

1. Covalent solid.
2. Octahedral structure.
3. Ionic solid with [PCl6]+ octahedral and [PCl4]- tetrahedral.
4. Ionic solid with [PCl4]+ tetrahedral and  [PCl6]- octahedral.

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Match the items in Columns I and II and mark the correct option.

Column I Column II
A. H2SO4 1. Highest electron affinity
B. CCl3NO2 2. Chalcogen
C. Cl2 3. Tear gas
D. Sulphur 4. Storage batteries

Codes:

A B C D
1. 4 3 1 2
2. 3 4 1 2
3. 4 1 2 3
4. 2 1 3 4
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Select the correct option based on statements below:
Assertion (A): Both rhombic and monoclinic sulphur exist as S8 but oxygen exists as O2.
Reason (R): Oxygen forms  pπ   -   pπ multiple bonds due to its small size and small bond length but  pπ   -   pπ bonding is not possible in sulphur.
    
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. Both (A) and (R) are False.
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Select the correct option based on statements below:
Assertion (A): SF6 cannot be hydrolysed but SF4 can be.
Reason (R): Six F-atoms in SF6 prevent the attack of H2O on sulphur atom of SF6
  
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
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Which of the following is incorrect regarding noble gases?

1. The atomic radii corresponds to van der Waal’s radii.

2. They have the largest size in a period.

3. They are also called inert gases.

4. They combine to form molecules.

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XeF4 is isostructural with :

1. ICl4-       

2. IBr2-                   

3. BrO3-

4. ICl3-

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 A xenon fluoride that does not exist is:

1. XeF4
2. XeF2
3. XeF3
4. XeF6

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In which compound does phosphorous have the lowest oxidation state?

1. H3PO3 

2. PCl3 

3. Ca3P2 

4. POF3

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The electron gain enthalpy values for O → O and O → O2– are –141 and 702 kJ  mol-1 , respectively. The correct statement about the formation of oxides is-

1. Higher the electron gain enthalpy lower is the lattice energy.
2. Higher the electron gain enthalpy higher is the lattice energy.
3. Higher the electron gain enthalpy higher is the stability of oxide.
4. O- is more stable than O2-

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PClacts as

1. Reducing agent

2. Oxidising agent

3. Dehydrating Agent

4. None of the above.

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