A compound that gives propyne on hydrolysis is -

1. ${\mathrm{Al}}_4{\mathrm{C}}_3$

2. ${\mathrm{Mg}}_2{\mathrm{C}}_3$

3. ${\mathrm{B}}_4\mathrm{C}$

4. ${\mathrm{La}}_4{\mathrm{C}}_3$

The most volatile compound among the following is -

1.  ${\mathrm{CH}}_4$

2.  ${\mathrm{SiH}}_4$

3.  ${\mathrm{GeH}}_4$

4.  ${\mathrm{SnH}}_4$

The coordination number of Al in aluminates, is-

Select the correct statement(s) regarding the following reaction sequence:

 
   

1.  The compound (A) is ${\left({\mathrm{CH}}_3\right)}_2{\mathrm{SiCl}}_2$

2.  The compound D is SiC

3.  The compound (B) is ${\left({\mathrm{CH}}_3\right)}_2\mathrm{Si}{\left(\mathrm{OH}\right)}_2$

4.  All of the above

A species among the following that decomposes easily is: -

A strong oxidizing agent among the following is -

1.  ${\mathrm{Tl}}^{3+}$

2.  ${\mathrm{Ga}}^{3+}$

3.  ${\ln }^{3+}$

4.  ${\mathrm{Al}}^{3+}$

From the following, the compound(s) that react(s) with \(\mathrm{BF}_3\) is/are -

${\mathrm{Na}}_2{\mathrm{B}}_4{\mathrm{O}}_7\cdot 10{\mathrm{H}}_2\mathrm{O}<mspace\; width="1em"></mspace>\underset{∆}{\overset{{740}^{\circ }\mathrm{C}}{\to }}<mspace\; width="1em"></mspace>2{\mathrm{NaBO}}_2+\left(\mathrm{X}\right)+10{\mathrm{H}}_2\mathrm{O}$
$\left(\mathrm{X}\right)+{\mathrm{CaF}}_2+{\mathrm{H}}_2{\mathrm{SO}}_4⟶\mathrm{Y}+{\mathrm{CaSO}}_4+{\mathrm{H}}_2\mathrm{O}$
$\left(\mathrm{Y}\right)+{\mathrm{NaBH}}_4⟶\left(\mathrm{Z}\right)+{\mathrm{NaBF}}_4$

Select the incorrect statement regarding compounds (X), (Y) and (Z).

1.  Compound (X) is ${\mathrm{B}}_2{\mathrm{O}}_3$ and compound (Z) contains two 3C - 2e bonds

2.  Compound (X) is ${\mathrm{B}}_2{\mathrm{O}}_3$ and compound (Y) contains one 3C - 2e bonds 

3.  Compound (Y) is Lewis acid and stable due to $p\pi -p\pi$ back bonding

4.  Compound (Z) reacts with excess of ${\mathrm{NH}}_3$ at high temperature gives inorganic graphite 

Hydrolysis of ${\mathrm{BCl}}_3$ gives X which on treatment with sodium carbonate produces Y. X and Y, respectively, are 

1.  ${\mathrm{H}}_3{\mathrm{BO}}_3<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NaBO}}_2$

2.  ${\mathrm{H}}_3{\mathrm{BO}}_3<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{Na}}_2{B}_4{O}_7$

3.  ${\mathrm{B}}_2{\mathrm{O}}_3<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{NaBO}}_2$

4.  $B_2{O}_3<mspace\; width="1em"></mspace>\mathrm{and}<mspace\; width="1em"></mspace>{\mathrm{Na}}_2{B}_4{O}_7$

Ionization enthalpy (${∆}_{\mathrm{i}}{\mathrm{H}}_1\mathrm{kJ}<mspace\; width="1em"></mspace>{\mathrm{mol}}^{-1}$) for the elements of Group 13 follows the order.