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2. | ![]() |
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4. | ![]() |
| List-I (Reaction) |
List-II (Reagents/ Condition) |
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| A. | ![]() |
I. | ![]() |
| B. | ![]() |
II. | \(\mathrm{CrO}_3\) |
| C. | ![]() |
III. | \(\begin{aligned} & \mathrm{KMnO}_4 \\ & \mathrm{KOH}, \Delta \end{aligned}\) |
| D. | ![]() |
IV. | \(\mathrm{(i) \mathrm{O}_3\\ (ii) \mathrm{Zn}-\mathrm{H}_2 \mathrm{O}}\) |
| 1. | \(\text { A-III, B-I, C-II, D-IV }\) |
| 2. | \(\text { A-IV, B-I, C-II, D-III }\) |
| 3. | \(\text { A-I, B-IV, C-II, D-III }\) |
| 4. | \(\text { A-IV,B-I, C-III, D-II }\) |
| 1. | Alkaline copper sulphate |
| 2. | Alkaline solution of sodium potassium tartrate (Rochelle's salt) |
| 3. | Aqueous sodium citrate |
| 4. | Aqueous copper sulphate |
| List-I (Reagent) |
List-II (Name of the reaction) |
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| A. | \(\mathrm{{H}_2, {Pd}-{Ba}S {O}_4}\) | I. | Gattermann-Koch reaction |
| B. | \(\mathrm{{(i) \; {CrO}_2 {Cl}_2, {CS}_2\\ (ii) ~{H}_2 {O}/H^+}}\) | II. | Reimer-Tiemann reaction |
| C. | \(\mathrm{{CO, HCl, Anhyd.~\\ {AlCl}_3 / {CuCl}}}\) | III. | Etard reaction |
| D. | \(\mathrm{{CHCl}_3, {NaOH}}\) | IV. | Rosenmund reduction |
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| 4. | ![]() |
| 1. | 2. | ||
| 3. | 4. |
| 1. | \(\mathrm{HC\equiv C^-~Na^+}\) | 2. | |
| 3. | 4. | \(\mathrm{C_4H_{10}}\) |
| Statement I | The boiling points of aldehydes and ketones are higher than hydrocarbons of comparable molecular masses because of weak molecular association in aldehydes and ketones due to dipole-dipole interactions. |
| Statement II | The boiling points of aldehydes and ketones are lower than the alcohols of similar molecular masses due to the absence of H-bonding. |
| 1. | Statement I is incorrect but Statement II is correct. |
| 2. | Both Statement I and Statement II are correct. |
| 3. | Both Statement I and Statement II are incorrect. |
| 4. | Statement I is correct but Statement II is incorrect. |
The correct IUPAC name of the following compound is:

| 1. | 2-Ethylhex-3-en-4-one | 2. | 4-Methylhex-3-en-2-one |
| 3. | 4-Ethylpent-3-en-2-one | 4. | 3-Methylhex -3-en-4-one |