Which of the following happens when NH4OH is added gradually to the solution containing 1M A2+ and 1M B3+ ions?
Given: \(\mathrm{K}_{\mathrm{sp}}\left[\mathrm{~A}(\mathrm{OH})_2\right]=9 \times 10^{-10} \text {}\)
\(\mathrm{K}_{\mathrm{sp}}\left[\mathrm{~B}(\mathrm{OH})_3\right]=27 \times 10^{-18} \text { at } 298 \mathrm{~K} .\)
 
1. B(OH)3 will precipitate before A(OH)2
2. A(OH)2 and B(OH)3 will precipitate together
3. A(OH)2 will precipitate before B(OH)3
4. Both A(OH)2 and B(OH)3 do not show precipitation with NH4OH
Subtopic:  Solubility Product | Common Ion Effect |
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Level 2: 60%+
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Why \(NH_4Cl\) is added before \(NH_4OH\) for the ppt. of \(Fe^{3+}\) ions?
1. To decrease \(OH^-\) ion concentration
2. To increase \(Cl^-\)ion concentration
3. To increase \(NH^+_4\) ion concentration
4. To decrease \(H^+\) ion concentration
Subtopic:  Common Ion Effect |
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Level 3: 35%-60%
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40% HI undergoes decomposition to form H₂ and I₂ at 300 K. Find the value of ΔG° for this decomposition reaction at 1 atm pressure in J mol⁻¹ (nearest integer).

(R = 8.31 J K⁻¹ mol⁻¹)


1. 2720 
2. 2740 
3. 2640 
4. 2520 
Subtopic:  Common Ion Effect |
Level 3: 35%-60%
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An aqueous solution contains an unknown concentration of Ba2+. When 50 mL of a 1 M solution of Na2SO4 is added, BaSO4 just begins to precipitate. The final volume is 500 mL. The solubility product of BaSO4 is 1 × 10–10. What is the original concentration of Ba2+ ?

1. 5 × 10–9 M

2. 2 × 10–9 M

3. 1 × 10–9 M

4. 1.0 × 10–10 M

Subtopic:  Common Ion Effect |
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Level 2: 60%+
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In aqueous solution, the ionization constants for carbonic acid are
\(K_{1} = 4.2 \times 10^{- 7}\) and \(K_{2} = 4.8 \times 10^{- 11}\)
The correct statement for a saturated 0.034 M solution of the carbonic acid is:

1. The concentration of H+ is double that of CO32
2. The concentration of CO32 is 0.034 M.
3. The concentration of CO32 is greater than that of HCO3
4. The concentration of H+ and HCO3 are approximately equal.
Subtopic:  Common Ion Effect |
 53%
Level 3: 35%-60%
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