The solubility product of Pbl2 is 8.0 × 10–9 . The solubility of lead iodide in 0.1 molar solution of lead nitrate is x × 10–6 mol/L. The value of x is:

(Rounded off to the nearest integer) [Given: 2=1.41 ] 

1. 154 2. 423
3. 282 4. 141

Subtopic:  Solubility Product |
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Arrange the following solution in the decreasing order of pOH :

(A). 0.01 M HCl

(B). 0.01 M NaOH

(C). 0.01 M CH3COONa

(D). 0.01 M NaCl

1. (B) > (C) > (D) > (A)

2. (A) > (C) > (D) > (B)

3. (B) > (D) > (C) > (A)

4. (A) > (D) > (C) > (B)

Subtopic:  pH calculation |
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The correct expression for the following reaction is:

Fe2N(s) + \(\frac{3}{2}\)H2(g) \(\leftrightharpoons \) 2Fe(s) + NH3(g)

1. Kc=Kp(RT) 2. Kc=Kp(RT)-3/2
3. Kc=Kp(RT)-1/2 4. Kc=Kp(RT)1/2
Subtopic:  Kp, Kc & Factors Affecting them |
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The variation of the equilibrium constant with temperature is given below :

Temperature               Equilibrium Constant

T1=25°C                   K1=100

T2=100°C                 K2=100

The values of H°,G°atT1andG°atT2inkJmol-1 respectively are close to: [use R=8.314 JK-1mol-1]

1. 28.4, -7.14 and -5.71

2. 0.64, -7.14 and -5.71

3. 0.64, -5.71 and -14.29

4. 28.4, -5.71 and -14.29

Subtopic:  Kp, Kc & Factors Affecting them |
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Given that the equilibrium constant (KC) at 800 K for the reaction \(N_2(𝑔)+3H_2(𝑔)⇋2NH_3(𝑔)\) is 64. What is the equilibrium constant Kat the same temperature for the reaction \(NH_3(g) ⇌ \dfrac{1}{2}N_2(g) + \dfrac{3}{2}H_2(g)\)?

1.  \(\dfrac{1}{4}\) 2. \(\dfrac{1}{8}\)
3. 8 4. \(\dfrac{1}{64}\)
Subtopic:  Introduction To Equilibrium |
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Find the molar solubility of AB₂ in pure water, given:

Kₛₚ = 3.20 × 10⁻¹¹

Assume that neither ion reacts with water.

1. 2 × 10-4 mol L-1

2. 4 × 10-4 mol L-1

3. 6 × 10-4 mol L-1

4. 8 × 10-4 mol L-1

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The pH of an ammonium phosphate solution, if the pKa of phosphoric acid and the pKb of ammonium
hydroxide are 5.23 and 4.75 respectively, is:

1. 8 2. 6
3. 7 4. 10
Subtopic:  pH calculation |
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The \(p K_a\) of a weak acid (HA) and \(p K_b\) of a weak base (BOH) are 3.2 and 3.4, respectively.
The pH of their salt (AB) solution is:

1. 7.0

2. 1.0

3. 7.2

4. 6.9

Subtopic:  pH calculation |
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Given that the pH of a 0.1 M solution of acid HQ is 3, the ionization constant \(K_a\) of the acid is:

1. 1 × 10–3 2. 1 × 10–5
3. 1 × 10–7 4. 3 × 10–1
Subtopic:  Ionisation Constant of Acid, Base & Salt |
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If the equilibrium constant \(\left(K_c\right)\) for the reaction \(\mathrm{N}_2(\mathrm{g})+\mathrm{O}_2(\mathrm{g}) \rightarrow 2 \mathrm{NO}(\mathrm{g})\) at temperature \(T\) is \(4 \times10^{-4}\) then what will be the value of \(K_c\) for the reaction, \(\mathrm{NO}(\mathrm{g}) \rightarrow \frac{1}{2} \mathrm{N}_2(\mathrm{g})+\frac{1}{2} \mathrm{O}_2(\mathrm{g})\) ?

1. \(2.5 \times10^{2}\)
2. \(4 \times10^{-4}\)
3. \(50.0\)
4. \(0.02\)

Subtopic:  Kp, Kc & Factors Affecting them |
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