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Among the following solvents, silver chloride is most soluble in:

1. \(0.1 \mathrm{~mol} ~\mathrm{dm}^{-3}~ \mathrm{AgNO}_3 \text { solution }\)
2. \(0.1 \mathrm{~mol} ~\mathrm{dm}^{-3}~ \mathrm{HCl} \text { solution }\)
3. \(\mathrm{H}_2 \mathrm{O}\)
4. Aqueous ammonia

Subtopic:  Common Ion Effect |
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The value of the pH of \(0.01 \) \(\text{mol dm}^{-3}   \)\(\text{CH}_3\text{COOH}\) \(\left(K_a=1.74 \times 10^{-5}\right)\)  is:

1. 3.4 2. 3.6
3. 3.9 4. 3.0
Subtopic:  pH calculation |
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Which of the following alternatives best describes the reaction A ⇌ B at its halfway point?
1. \(\Delta G^{\ominus}=0\)
2. \(\Delta G^{\ominus}>0\)
3. \(\Delta G^{\ominus}<0\)
4. \(\Delta G^{\ominus}=-RTlnK\)

Subtopic:  Kp, Kc & Factors Affecting them |
Level 3: 35%-60%
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On increasing the pressure, the direction in which the gas phase reaction proceeds to re-establish equilibrium is predicted by applying Le-Chatelier's principle. Consider the reaction,

N2(g)+3H2(g)2NH3(g)

Which of the following is correct, if the total pressure at which the equilibrium is established is increased without changing the temperature?

1. K will remain the same.
2. K will decrease.
3. K will increase.
4. K will increase initially and then decrease, when pressure is very high.

Subtopic:  Le Chatelier's principle |
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The addition of a small amount of argon at a constant volume will not affect the equilibrium of the following reaction:

1. H2(g)+I2(g)⇌2HI(g)
2. PCl5(g)⇌ PCl3(g)+Cl2(g)
3. N2(g)+3H2(g)⇌2NH3(g)
4. The equilibrium will remain unaffected in all the three cases.

Subtopic:  Le Chatelier's principle |
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 At 450 K, Kp= 2.0 × 1010 bar-1 for the given reaction at equilibrium

2SO2(g) + O2(g)  2SO3(g) 

The value of  Kc at this temperature would be :

1. 7.48 ×1012 M-1
2. 6.56 × 1011 M-1
3. 7.48 × 1011 M-1
4. 1.23 × 1010 M-1

Subtopic:  Kp, Kc & Factors Affecting them |
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For the reaction: FeO(s) + CO(g)  Fe(s) +CO2(g), Kp = 0.265  at 1050 K. If the initial partial pressures are pCO= 1.4 atm and pCO2= 0.80 atm, the partial pressure of CO2 at equilibrium at 1050 K would be:

1. 4.61 atm 2. 1.74 atm
3. 0.46 atm 4. 0.17 atm
Subtopic:  Kp, Kc & Factors Affecting them |
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For the reaction, 

N2 (g) + 3H2(g)  2NH3 (g); 
Kc= 0.061 mol-2L2  at 500K. At a particular instant of time, [N2] = 3.0 mol L
–1, [H2] = 2.0 mol L–1  and
[NH3] = 0.5 mol L
–1 .

True statement among the following is: 

1. Reaction is at equilibrium.

2. Reaction will proceed in the forward direction.

3. Reaction will proceed in the backward direction.

4. Can't predict the direction of the reaction.
 

Subtopic:  Kp, Kc & Factors Affecting them |
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At 1127 K and 1 atm pressure, a gaseous mixture of CO and CO2 in equilibrium with solid carbon has 90.55% CO by mass. 

C(s) + CO2(g) 2CO(g)

At the specified temperature, Kc for this reaction would be:

1. 0.25 mol L-1
2. 0.34 mol L-1
3. 0.15 mol L-1
4. 1.25 mol L-1

Subtopic:  Kp, Kc & Factors Affecting them |
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(a) Cl2(g)  ⇌ 2Cl(g) ; Kc = 5.0×10-39 mol/L
(b) Cl2(g)   +   2NO(g)   ⇌   2NOCl(g)   ;   Kc =3.7×108 mol/L
(c) Cl2(g) +   2NO2(g)   ⇌   2NO2Cl(g)   ;  
Kc=1.8  mol/L
In which of the reactions given above, will there be an appreciable concentration of both reactant (s) and product (s)?
1. Only reaction (a)
2. Both reactions (a) and (b)  
3. Only reaction (c)
4. Only reaction (b) 
Subtopic:  Kp, Kc & Factors Affecting them |
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