Consider the reversible exothermic reaction:

N₂(g) + 3H₂(g) \(\rightleftharpoons\) 2NH₃(g) + heat 

Under which of the following conditions will the equilibrium shift in the forward direction (towards the formation of ammonia)?

1. Increasing the concentration of \(N H_3 ( g )\)
2. Decreasing the pressure
3. Decreasing the concentration of \(N_2(g) ~and~H_2(g)\)
4. Increasing the pressure and decreasing the temperature

For a given exothermic reaction, K_p and K_p^’ are the equilibrium constants at temperatures T₁ and T₂ respectively. Assuming that the heat of reaction is constant in temperatures range between T₁ and T₂, it is readily observed that:
1. $K_p>K_p^{\text{'}}$
2. $K_p<K_p^{\text{'}}$
3. $K_p=K_p^{\text{'}}$
4. $K_p=\frac{1}{K_p^{\text{'}}}$

Which of the following species is least likely to act as a Lewis base?

The strongest acid among the following compounds is:

pH of a saturated solution of Ba(OH)₂ is 12. The value of solubility product K_sp of Ba (OH)₂ is:
1. $3.3\times {10}^{-7}$
2. $5.0\times {10}^{-7}$
3. $4.0\times {10}^{-6}$
4. $5.0\times {10}^{-6}$

Which of the following equimolar solutions, prepared separately, will have the highest pH?

Buffer solutions have constant acidity and alkalinity because:
 

A buffer solution is prepared in which the concentration of NH₃ is 0.30 M and the concentration of  $N{H}_4^{+\hspace{0.17em}}$ is 0.20 M. If the equilibrium constant, K_b for NH₃ equals 1.8×10^–5, then what is the pH of this solution? 
(log 1.8 = 0.25; log 0.67 = –0.176)

1.  9.43
2.  11.72
3.  8.73
4.  9.08

What conditions favor the formation of 2XY₄(g) in the reaction X₂(g) + 4Y₂(g) ⇋ 2XY₄(g), considering that the enthalpy change (ΔH) is negative?

For the reaction ${\mathrm{N}}_2\left(\mathrm{g}\right)$ $+$ ${\mathrm{O}}_2\left(\mathrm{g}\right)\leftrightharpoons 2\mathrm{NO}\left(\mathrm{g}\right)$ the equilibrium constant is K₁. The equilibrium constant is K₂ for the reaction  $2\mathrm{NO}\left(\mathrm{g}\right)$ $+$ ${\mathrm{O}}_2\left(\mathrm{g}\right)$ $\leftrightharpoons 2{\mathrm{NO}}_2\left(\mathrm{g}\right)$ $$
The value of K for the reaction given below will be:
${\mathrm{NO}}_2\left(\mathrm{g}\right)\leftrightharpoons \frac{1}{2}{\mathrm{N}}_2\left(\mathrm{g}\right)$ $+{\mathrm{O}}_2\left(\mathrm{g}\right)$ $$

1.  $\frac{1}{4}$ $\left(4\right)$ ${\mathrm{K}}_1$ ${\mathrm{K}}_2$

2.  ${\left[\frac{1}{{\mathrm{K}}_1{\mathrm{K}}_2}\right]}^{1/2}$

3.  $\frac{1}{\left({\mathrm{K}}_1{\mathrm{K}}_2\right)}$

4.  $\frac{1}{\left(2{\mathrm{K}}_1{\mathrm{K}}_2\right)}$