The shape/structure of [XeF5]– and XeO3F2, respectively, are :
1. Pentagonal planar and trigonal bipyramidal
2. Trigonal bipyramidal and pentagonal planar
3. Octahedral and square pyramidal
4. Trigonal bipyramidal and trigonal bipyramidal
Of the species, NO , NO+, NO2+ and NO– , the one with minimum bond strength is:
1. NO2+
2. NO+
3. NO
4. NO–
The molecule in which hybrid MOs involve only one d-orbital of the central atom is:
| 1. | \(X e F_{4}\) | 2. | \(\left[ N i (CN)_{4} \right]^{2 -}\) |
| 3. | \(B r F_{5}\) | 4. | \(\left[ C r F_{6} \right]^{3 -}\) |
The structure of PCl5 in the solid state is:
1. Square pyramidal.
2. Tetrahedral [PCl4]+ and octahedral [PCl6]–
3. Square planar [PCl4] and octahedral [PCl6]–
4. Trigonal bipyramidal.
The compound that has the largest H–M–H bond angle (M=N, O, S, C), is:
| 1. | H2O | 2. | CH4 |
| 3. | NH3 | 4. | H2S |
The isostructural pairs among the following are:
| A. | \( \mathrm{SO}_{4}^{2-} and \ \mathrm{CrO}_{4}^{2-}\) |
| B. | \(\mathrm{SiCl}_{4} \ and \ \mathrm{TiCl}_{4}\) |
| C. | \(\mathrm{NH}_{3} \ and \ \mathrm{NO}_{3}^{-} \) |
| D. | \(\mathrm{BCl}_{3} \ and \ \mathrm{BrCl}_{3}\) |
1. C and D only
2. A and B only
3. A and C only
4. B and C only
According to molecular orbital theory, which of the following molecules is not expected to be stable?
| 1. | \(\mathrm{He}_2^{2+}\) | 2. | \(\mathrm{He}_2^{+}\) |
| 3. | \(\mathrm{H}_2^{-}\) | 4. | \(\mathrm{H}_2^{2-}\) |
How many lone pairs of electrons are present in \({I }_{3}^{-}\) ion?
| 1. | Three (3) | 2. | Six (6) |
| 3. | Nine (9) | 4. | Twelve (12) |
| 1. | \(\text {He}_{2}^{+} \) | 2. | \(\text {He}_{2}^{-}\) |
| 3. | \(\text {Be}_{2}\) | 4. | \(\text O_{2}^{2 -}\) |
In molecule, the hybridization of carbon 1,2,3 and 4 respectively are :
1.
2.
3.
4.