The vapour pressure of pure water at 298K is 23.76mm. The vapour pressure of a solution of sucrose(C12H22O11) in 5.56 moles of water is 23.392mm Hg. The mass of sucrose in the solution is

1. 15 g

2. 45 g

3. 30 g

4. 37.5 g

Subtopic:  Relative Lowering of Vapour Pressure |
 58%
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Among the following options, 0.1 M aqueous solution that will have the lowest freezing point is-

1. Potassium Sulphate. 2. Sodium chloride.
3. Urea. 4. Glucose.

Subtopic:  Depression of Freezing Point |
 68%
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The vapour pressure of toluene is 59.1 torr at 313.75 K and 298.7 torr at 353.15 K. Calculate, the molar heat of vaporisation.

1. 37888 J mol-1

2. 27188 J mol-1

3.  12834 J mol-1

4. 571328 J mol-1

Subtopic:  Raoult's Law |
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The vapour pressure of a pure liquid solvent A is 0.80 atm. When a non-volatile substance B is added to the solvent, its vapour pressure drops to 0.60 atm.
Mole fraction of the component B in the solution is:

1. 0.50 2. 0.75
3. 0.40 4. 0.25
Subtopic:  Relative Lowering of Vapour Pressure |
 72%
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The lowest boiling point, if concentration is fixed at 0.1 M in aqueous solution, is given by which of the following solutions?

a. K2SO4

b. NaCl

c. Urea

d. Glucose

1. a, b

2. b, c

3. c, d

4. d, a

Subtopic:  Elevation of Boiling Point |
 65%
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The boiling point of acetic acid is 118.1°C and its latent heat of vaporisation is 121 cal/gm. A solution containing 0.4344 gm anthracene in 44.16 gm acetic acid boils at 118.24°C. What is the molecular wt. of anthracene ?

1. 122

2. 178

3. 105

4. 154

Subtopic:  Elevation of Boiling Point |
 65%
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Which solution will have the highest boiling point ?

1. 1 (M) C6H12O6 solution

2. 1 (M) NaCl solution

3. 1 (M) BaCl2 solution

4. 1 (M) CO(NH2)2 solution

Subtopic:  Van’t Hoff Factor |
 63%
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A 2.0% solution by weight of urea in water shows a boiling point elevation of 0.18 deg [Molecular weight of urea=60]. Calculate the latent heat of vaporization per gram of water.

1. 495.3 cal/g

2. 560.3 cal/g

3. 525.8 cal/g

4. 501.3 cal/g

Subtopic:  Elevation of Boiling Point |
 52%
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A solution of 18 g of glucose in 1000 g of water is cooled to -0.2 oC. The amount of ice separating out from this solution is -

[Kf(H2O) = 1.86 K molal-1]

1. 70 g 2. 140 g
3. 90 g 4. 210 g
Subtopic:  Depression of Freezing Point |
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The partial pressure of ethane over a saturated solution containing 6.56 X 10-2 g of ethane is 1 bar. If the solution contains 5.00 X 10-2 g of ethane, then what shall be the partial pressure of the gas?

1. 0.76 bar

2. 0.16 bar

3. 1.16 bar

4. 3.12 bar

Subtopic:  Concentration Terms & Henry's Law |
 74%
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